(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a

(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Suppliers list
Company Name: Shanghai Daken Advanced Materials Co.,Ltd
Tel: +86-371-66670886
Email: info@dakenam.com
Products Intro: Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
CAS:284472-79-3
Purity:99% Package:100g ;1KG ;5KG 25KG
Company Name: Alchem Pharmtech,Inc.
Tel: 8485655694
Email: sales@alchempharmtech.com
Products Intro: Product Name:(S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine
Purity:97+% Package:1g;10g;100g;;1kg Remarks:Z-19308
Company Name: CR Corporation Lomited
Tel:
Email: fred.wen@crcorporation.cn
Products Intro: Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
CAS:284472-79-3
Company Name: CD Chemical Group Limited
Tel: +8615986615575
Email: info@codchem.com
Products Intro: CAS:284472-79-3
Purity:0.99 Package:1000KG;100KG;5KG;1KG
Company Name: Alfa Chemistry
Tel: +1-5166625404
Email: Info@alfa-chemistry.com
Products Intro: Product Name:(S)-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl)piperidine
CAS:284472-79-3
Remarks:https://www.alfachemic.com/catalysts/product/s-1-dinaphtho-2-1-d-1-2-f-1-3-2-dioxaphosphepin-cas-284472-79-3-120290.html
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Basic information
Reaction
Product Name:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a
Synonyms:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine, min. 97% (S)-PipPhos;97% (S)-PipPhos;1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxa-phosphepin-4-yl)piperidine;(S)-PipPhos;1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl-piperidine;(S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)piperidine 97%;-1-(Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-yl);1-(11bS)-Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin- 4-ylpiperidine,99%e.e.
CAS:284472-79-3
MF:C25H22NO2P
MW:399.43
EINECS:
Product Categories:Chiral Phosphine;CPN
Mol File:284472-79-3.mol
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Structure
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Chemical Properties
Melting point 206-213 °C
Boiling point 597.5±33.0 °C(Predicted)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka1.67±0.20(Predicted)
form Powder
color white
Sensitive moisture sensitive
Safety Information
MSDS Information
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Usage And Synthesis
Reaction
  1. Ligand used in the enantioselective rhodium catalyzed low pressure high activity hydrogenation of α–dehydroaminoesters, enamides, and dimethylitaconate.
  2. Ligand used in asymmetric hydrogenation of 2-substituted N-protected indoles using Rhodium-based catalysts. 
Reactions of 284472-79-3
(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a Preparation Products And Raw materials
Tag:(S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a(284472-79-3) Related Product Information
(R)-MONOPHOS (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)[(1R)-1-PHENYLETHYL]AMINE (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1R)-1-PHENYLETHYL]AMINE,DICHLOROMETHANE ADDUCT (S)-(-)-2,2'-Bis[di(3,5-xylyl)phosphino]-1,1'-binaphthyl (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a