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| TROPONE Basic information |
Product Name: | TROPONE | Synonyms: | TROPONE;2,4,6-Cyclo-heptatriene-1-one;2,4,6-Cycloheptatriene-1-one;Cycloheptatrienone;Tropon;2,4,6-CYCLOHEPTATRIENONE;LABOTEST-BB LT00233179;Tropone,97% | CAS: | 539-80-0 | MF: | C7H6O | MW: | 106.12 | EINECS: | 208-725-6 | Product Categories: | | Mol File: | 539-80-0.mol | ![TROPONE Structure](CAS/GIF/539-80-0.gif) |
| TROPONE Chemical Properties |
Melting point | -7°C | Boiling point | 113 °C/15 mmHg (lit.) | density | 1.094 g/mL at 25 °C (lit.) | refractive index | n20/D 1.615(lit.) | Fp | >110°C | storage temp. | -20°C | form | Liquid | color | very deep brown | BRN | 1902335 |
| TROPONE Usage And Synthesis |
Uses | Tropone has been used in synthesis of:
- bicyclic δ-lactones via heterocyclic carbine-catalyzed [8+3] annulation pathway
- 6,7-benzobicyclo [3.2.2] nona-3,6,8-trien-2-one via thermal addition to bezyne
| Synthesis Reference(s) | Journal of the American Chemical Society, 78, p. 5442, 1956 DOI: 10.1021/ja01601a077 The Journal of Organic Chemistry, 29, p. 960, 1964 Organic Syntheses, Coll. Vol. 9, p. 396, 1998 | General Description | Metal-catalyzed [6+3] cycloaddition of tropone with azomethine ylides has been reported. |
| TROPONE Preparation Products And Raw materials |
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