LITHIUM ANTIMONIDE

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Products Intro: Product Name:Formalin;lithium antimonide
CAS:12057-30-6
Purity:0.99 Package:25KG,200L
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Products Intro: Product Name:LITHIUM ANTIMONIDE
CAS:12057-30-6
Purity:99% Package:5g;25g;100g;500g
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LITHIUM ANTIMONIDE Basic information
Product Name:LITHIUM ANTIMONIDE
Synonyms:antimony,compd.withlithium(1:3);antimony, compound with lithium (1:3);Einecs 235-021-6;LITHIUM ANTIMONIDE
CAS:12057-30-6
MF:Li3Sb
MW:142.58
EINECS:235-021-6
Product Categories:
Mol File:12057-30-6.mol
LITHIUM ANTIMONIDE Structure
LITHIUM ANTIMONIDE Chemical Properties
EPA Substance Registry SystemAntimony, compd. with lithium (1:3) (12057-30-6)
Safety Information
MSDS Information
LITHIUM ANTIMONIDE Usage And Synthesis
SynthesisTo obtain Li3As and Li3Sb, a suspension of freshly powdered As (or Sb) in anhydrous liquid NH3 is prepared. A solution of Li in dried liquid ammonia is added, in small portions, to the suspension. The reaction begins on shaking. Its termination is indicated by the appearance of a blue color in the supernatant fluid, due to a slight excess of Li. The NH3 is boiled out, with the last traces removed by vacuum. The products are either the brown Li3As powder (very air sensitive; must be stored under pure N2 or Ar) or blue-gray β-Li3Sb powder. The particle size of the latter can be increased by heating at 650°C. Another modification, α-Li3Sb, is obtained by quenching of the melt (m.p. between 1150 and 1300°C) under Ar in a thick-walled iron crucible with welded-on lid.
LITHIUM ANTIMONIDE Preparation Products And Raw materials
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LITHIUM ANTIMONIDE