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| | SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Basic information |
| Product Name: | SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) | | Synonyms: | SAMARIUM TRIS(HEXAMETHYLDISILAZIDE);TRIS[N,N-BIS(TRIMETHYLSILYL)AMIDE]SAMARIUM(III);Tris[N,N-bis(trimethylsilyl)amide]samarium;Tris[N,N-bis(triMethylsilyl)aMide]saMariuM [[(CH3)3Si]2N]3SM;1,1,1-Trimethyl-N-(trimethylsilyl)silanamine samarium(III) salt;Tris(1,1,1,3,3,3-hexamethyldisilazanato)samarium;samarium tris(hexamethylsilazide);Tris[N,N-bis(trimethylsilyl)amide]samarium [[(CH3)3Si]2N]3Sm FW 631.51 M.p. 93-1060C | | CAS: | 35789-01-6 | | MF: | C6H19NSi2Sm | | MW: | 311.76 | | EINECS: | | | Product Categories: | Samariun;SamariumVapor Deposition Precursors;Precursors by Metal;Chemical Synthesis;Catalysis and Inorganic Chemistry | | Mol File: | 35789-01-6.mol |  |
| | SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Chemical Properties |
| Melting point | 93-106 °C(lit.) | | Boiling point | 83-4°C/1x10-4mmHg | | Fp | 36 °F | | form | solid |
| | SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Usage And Synthesis |
| Uses | Reactant for synthesis of:
- Heterobimetallic samarium(III) complexes
- Binuclear lanthanide complexes
Catalyst for:
- Coordination polymerization of renewable butyrolactone-based vinyl monomers
- Intramolecular hydroamination of non-activated alkenes
- Chiral functionalization of isoxazoles
- Enantioselective hydroamination / cyclization
| | reaction suitability | core: samarium
reagent type: catalyst |
| | SAMARIUM TRIS(HEXAMETHYLDISILAZIDE) Preparation Products And Raw materials |
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