13080-86-9

2,2'-双[4-(4-氨基苯氧基苯基)]丙烷(13080-86-9)质谱(MS)

分子式:C27H26N2O2

分子量: 410.51

InChI:InChI=1S/C27H26N2O2/c1-27(2,19-3-11-23(12-4-19)30-25-15-7-21(28)8-16-25)20-5-13-24(14-6-20)31-26-17-9-22(29)10-18-26/h3-18H,28-29H2,1-2H3

InChIKey: KMKWGXGSGPYISJ-UHFFFAOYSA-N

Smiles:C(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C1=CC=C(OC2=CC=C(N)C=C2)C=C1)(C)C

Mass

MS-IW-4845          
4,4'-(isopropylidenebis(p-phenyleneoxy))dianiline
C27H26N2O2          (Mass of molecular ion:    410)

   Source Temperature: 190 °C
   Sample Temperature: 200 °C
   Direct, 75 eV

      65.0       3.4
      80.0       3.0
      92.0       1.6
      93.0       3.6
     108.0      20.4
     109.0       2.3
     152.0       1.3
     165.0       1.8
     167.0       1.1
     178.0       2.7
     179.0       3.1
     181.0       1.0
     182.0       2.1
     197.0       1.1
     197.5       9.9
     198.0       3.3
     205.0      13.6
     205.5       2.9
     206.0       1.7
     210.0       7.3
     211.0       1.4
     226.0       3.0
     287.0       4.3
     288.0       1.2
     395.0     100.0
     396.0      29.2
     397.0       4.7
     410.0      77.2
     411.0      23.5
     412.0       3.8

400 MHz in CDCl3

¹H NMR	399.65 MHz
C₂₇ H₂₆ N₂ O₂	0.041 g : 0.5 ml CDCl₃
4,4'-(isopropylidenebis(p-phenyleneoxy))dianiline

    Assign.     Shift(ppm)

      A             7.121
      B             6.854
      C             6.812
      D             6.643
      E             3.52
      F             1.626

     Hz     ppm     Int.

   2853.64   7.141     48
   2850.59   7.133    425
   2848.39   7.128    131
   2843.87   7.116    152
   2841.80   7.111    463
   2838.50   7.103     52
   2747.31   6.875     47
   2744.02   6.867    451
   2741.70   6.861    143
   2737.43   6.850    172
   2735.35   6.845    529
   2731.69   6.836     64
   2729.74   6.831     63
   2726.68   6.823    498
   2724.49   6.818    144
   2719.97   6.806    141
   2717.90   6.801    412
   2714.60   6.793     44
   2661.87   6.661     61
   2658.45   6.652    559
   2656.13   6.647    156
   2651.86   6.636    153
   2649.90   6.631    430
   2646.24   6.622     42
   1404.79   3.516     33
    650.02   1.627   1000

in CDCl3