2-氨基6-甲基吡啶(1824-81-3)核磁图(13CNMR)
InChI:InChI=1S/C6H8N2/c1-5-3-2-4-6(7)8-5/h2-4H,1H3,(H2,7,8)
InChIKey: QUXLCYFNVNNRBE-UHFFFAOYSA-N
Smiles:C1(N)=NC(C)=CC=C1
-
Mass
MS-NW-4672
6-methyl-2-pyridylamine
C6H8N2 (Mass of molecular ion: 108)
Source Temperature: 250 °C
Sample Temperature: 180 °C
Reservoir, 75 eV
15.0 1.3
18.0 2.3
26.0 1.0
27.0 2.8
28.0 5.1
37.0 2.4
38.0 5.4
39.0 17.4
40.0 4.5
41.0 9.6
42.0 8.2
43.0 2.3
50.0 1.6
51.0 2.7
52.0 3.9
53.0 6.8
54.0 4.0
62.0 1.1
63.0 2.5
64.0 5.0
65.0 5.5
66.0 12.1
67.0 2.6
68.0 3.2
79.0 1.1
80.0 51.7
81.0 39.7
82.0 2.7
91.0 9.5
92.0 2.3
93.0 4.1
107.0 3.4
108.0 100.0
109.0 7.4
parameter in CDCl3
90 MHz in CDCl3
-
| 1H NMR |
300 MHz |
| C6 H8 N2
|
20 % in CDCl3
|
| 2-amino-6-methylpyridine
|
 |
Parameter ppm Hz
D(A) 6.13
D(B) 7.14
D(C) 6.32
J(A,B) 8.1
J(A,C) 1.2
J(B,C) 7.3
D(D) 5.23
D(E) 2.28
BELL,C.L. ET AL. J.HETEROCYCL.CHEM. 2, 420 (1965)
|
Hz ppm Int.
2149.82 7.166 79
2142.50 7.142 101
2141.77 7.139 100
2134.45 7.115 89
1900.22 6.334 92
1899.04 6.330 96
1892.89 6.310 88
1891.76 6.306 90
1843.59 6.145 95
1842.42 6.141 92
1835.50 6.118 90
1834.32 6.114 87
1569.02 5.230 667
684.02 2.280 1000
-
| 1H NMR |
89.56 MHz |
| C6 H8 N2
|
0.045 g : 0.5 ml CDCl3
|
| 6-methyl-2-pyridylamine
|
|
Assign. Shift(ppm)
A 7.288
B 6.477
C 6.282
D 4.6
E 2.357
|
Hz ppm Int.
660.94 7.380 102
653.56 7.298 151
653.00 7.292 137
645.44 7.207 142
583.38 6.514 147
582.88 6.509 119
576.00 6.432 118
575.50 6.426 95
566.25 6.323 142
565.69 6.317 111
558.94 6.241 85
558.19 6.233 120
557.56 6.226 91
411.75 4.598 38
211.13 2.358 1000