2,2,6,6-四甲基哌啶胺(36768-62-4)Raman光谱
InChI:InChI=1S/C9H20N2/c1-8(2)5-7(10)6-9(3,4)11-8/h7,11H,5-6,10H2,1-4H3
InChIKey: FTVFPPFZRRKJIH-UHFFFAOYSA-N
Smiles:N1C(C)(C)CC(N)CC1(C)C
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Mass
MS-NW-5764
4-amino-2,2,6,6-tetramethylpiperidine
C9H20N2 (Mass of molecular ion: 156)
Source Temperature: 250 °C
Sample Temperature: 190 °C
Reservoir, 75 eV
15.0 2.5
18.0 3.1
27.0 2.8
28.0 5.8
29.0 4.2
30.0 4.1
39.0 5.0
40.0 1.1
41.0 11.3
42.0 33.4
43.0 9.4
44.0 12.2
53.0 1.3
54.0 1.0
55.0 4.8
56.0 4.9
57.0 10.1
58.0 47.5
59.0 2.0
67.0 2.0
68.0 1.3
70.0 2.1
71.0 1.8
81.0 1.1
82.0 3.4
83.0 1.5
84.0 12.9
85.0 3.5
96.0 1.2
98.0 100.0
99.0 16.1
100.0 1.1
107.0 1.1
108.0 1.0
112.0 1.5
124.0 14.6
125.0 1.8
139.0 1.9
140.0 1.9
141.0 47.7
142.0 7.0
156.0 5.1
400 MHz in CDCl3
90 MHz in CDCl3
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| 1H NMR |
399.65 MHz |
| C9 H20 N2
|
0.05 ml : 0.5 ml CDCl3
|
| 4-amino-2,2,6,6-tetramethylpiperidine
|
 |
Assign. Shift(ppm)
A 3.083
B 1.790
C *1 1.186
D *1 1.122
E 0.818
|
Hz ppm Int.
1243.90 3.113 44
1236.08 3.093 47
1232.30 3.084 89
1228.52 3.074 46
1220.58 3.055 46
724.37 1.813 122
723.27 1.810 79
720.58 1.804 120
712.52 1.783 82
711.55 1.781 130
707.76 1.771 125
474.24 1.187 923
448.36 1.122 1000
338.87 0.848 90
327.03 0.819 161
315.06 0.789 85
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| 1H NMR |
89.56 MHz |
| C9 H20 N2
|
0.04 ml : 0.5 ml CDCl3
|
| 4-amino-2,2,6,6-tetramethylpiperidine
|
|
Assign. Shift(ppm)
A 3.074
B 1.79
C 1.187
D 1.123
E 1.08
F 0.84
J(A,F)=11.6HZ. J(A,B)=3.7HZ. J(B,F)=11.6HZ.
|
Hz ppm Int.
287.75 3.213 27
279.94 3.126 25
276.19 3.084 63
272.38 3.042 27
264.56 2.954 35
168.69 1.884 73
167.69 1.873 44
164.94 1.842 70
157.06 1.754 49
156.06 1.743 91
152.25 1.700 88
106.31 1.188 837
100.56 1.123 1000
97.13 1.085 378
85.25 0.952 63
84.69 0.946 62
72.94 0.815 90
61.13 0.683 38
60.56 0.677 36