What is the reaction mechanism of Trimethylsilyl trifluoromethanesulfonate?
May 11,2024
Studies on the mechanism of isomerisation of permethylated methyl d-glycopyranosides catalysed by Trimethylsilyl trifluoromethanesulfonate have shown that both cyclic and acyclic carbonyl ions appear to be intermediates in the isomerisation. The former appears to be a key intermediate in the formation of pyridine-type compounds as well as in the isomerisation of the α-glycosidic bond. On the other hand, the β-glycosidic bond seems to be isomerised mainly via acyclic carbonyl ions.
- Related articles
- Related Qustion
- Trimethylsilyl trifluoromethanesulfonate: applications in organic synthesis Jun 28, 2023
TMSOTf is a trifluoromethanesulfonate compound with a trimethylsilyl R-group. It is commonly used in organic synthesis and has similar reactivity to trimethylsilyl chloride
- What is Trimethylsilyl trifluoromethanesulfonate? Apr 14, 2021
Trimethylsilyl trifluoromethanesulfonate is composed by trifluoromethesulfonate and trimethylsilane group, under room pressure it is a colorless liquid.
Methyl methacrylate (MMA) is a monomer unsaturated ester. It has a variety of uses in polymer manufacturing.....
May 11,2024APICholesterol is a waxy substance found in the blood of all humans and animals.....
May 11,2024Biochemical EngineeringTrimethylsilyl trifluoromethanesulfonate
27607-77-8You may like
Trimethylsilyl trifluoromethanesulfonate manufacturers
- Trimethylsilyl trifluoromethanesulfonate
- $0.00 / 5KGS
- 2024-02-06
- CAS:27607-77-8
- Min. Order: 5KGS
- Purity: 99.5+%
- Supply Ability: 10ton/year
- Trimethylsilyl trifluoromethanesulfonate
- $0.00 / 1KG
- 2023-09-06
- CAS:27607-77-8
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 500000kg
- Trimethylsilyl trifluoromethanesulfonate
- $8.40 / 1KG
- 2023-06-15
- CAS:27607-77-8
- Min. Order: 1KG
- Purity: 99%
- Supply Ability: 50 tons