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1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота

1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота структура
27619-97-2
CAS №
27619-97-2
Химическое название:
1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота
английское имя:
1H,1H,2H,2H-Perfluorooctanesulfonic acid
Синонимы:
Perfluorohexyl ethyl sulfonic acid;Perfluorohexyl Ethyl sulphonic acid;3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluorooctanesulphonic acid;1H.1H.2H.2H-perfluorooctane;perfluorohexyl ethyl sulfonate;1H.1H.2H.2H-perfluorooctane sulfonate;(1H,1H,2H,2H)-Perfluorooctanesulfonic];2-(Perfluorohexyl)ethane-1-sulfonic acid;1H,1H,2H,2H-PERFLUOROOCTANESULFONIC ACID;2-(Perfluorohexyl)ethane-0-sulfonic acid
CBNumber:
CB3467468
Формула:
C8H5F13O3S
молекулярный вес:
428.17
MOL File:
27619-97-2.mol

1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота атрибут

плотность: 1,25 g/cm3
давление пара: 1.96Pa at 20℃
растворимость: Ацетон: мало растворим, хлороформ: мало растворим, ДМСО: мало растворим, метанол: мало растворим
форма: A low-melting solid
пка: 1.31±0.50(Predicted)
Растворимость в воде: 658 г/л при 20℃
InChI: InChI=1S/C8H5F13O3S/c9-3(10,1-2-25(22,23)24)4(11,12)5(13,14)6(15,16)7(17,18)8(19,20)21/h1-2H2,(H,22,23,24)
ИнЧИКей: VIONGDJUYAYOPU-UHFFFAOYSA-N
SMILES: C(S(O)(=O)=O)CC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F
FDA UNII: 9E5JL7S7WY
Система регистрации веществ EPA: 1-Octanesulfonic acid, 3,3,4,4,5,5,6,6,7,7,8,8,8-tridecafluoro- (27619-97-2)
безопасность
  • Заявления о рисках и безопасности
  • код информации об опасности(GHS)
Коды опасности C,Xi
Заявления о рисках 34
Заявления о безопасности 26-36/37/39-45
РИДАДР 3265
Примечание об опасности Corrosive
Класс опасности IRRITANT, CORROSIVE
кода HS 2904990090
символ(GHS) GHS hazard pictograms
сигнальное слово Danger
Заявление об опасности
пароль Заявление об опасности Класс опасности категория сигнальное слово пиктограмма предупреждение
H314 При попадании на кожу и в глаза вызывает химические ожоги. Разъедание/раздражение кожи Категория 1А, В, С Опасность GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
Внимание
P260 Не вдыхать газ/ пары/ пыль/ аэрозоли/ дым/ туман.
P271 Использовать только на открытом воздухе или в хорошо вентилируемом помещении.
P280 Использовать перчатки/ средства защиты глаз/ лица.

1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота химические свойства, назначение, производство

Описание

1H,1H,2H,2H-Perfluorooctanesulfonic acid (1H,1H,2H,2H-Perfluorooctanesulphonic acid) is an efficient fluorine-containing surfactant without perfluorooctane sulfonic acid, which has the characteristics of high temperature resistance, oxidant resistance, electrolytic stability, etc. It can reduce the concentration of chromic acid in plating workshop and inhibit the precipitation of chromic acid and chromium mist.

Химические свойства

White to Brown Solid.

Использование

1H,1H,2H,2H-Perfluorooctanesulfonic acid is an aliphatic compound for fluorinated surfactant synthesis.

прикладной

1H,1H,2H,2H-Perfluorooctanesulfonic acid (1H,1H,2H,2H-Perfluorooctanesulphonic acid) can functionalize gallium nitride (GaN) to tune the optical properties, which can potentially be used in chemical sensor based applications. It can modify the surface characteristics of copper substrates that find usage in printed circuit boards as copper foils. It can also be coated on the indium tin oxide substrate, which may be utilized in organic light emitting diodes (OLEDs) and organic photovoltaics (OPVs).

Общее описание

1H,1H,2H,2H-Perfluorooctanesulfonic acid is a fluoroalkyl phosphonic acid that contains 8 fluorinated carbon atoms. It forms a self-assembled layer on the substrate due to the adhesion of the phosphonates. The surface adhesion is a component of the acid base linkage that is enhanced by the hydroxyl groups.

Токсикология

Toxicological studies of 1H,1H,2H,2H-Perfluorooctanesulfonic acid (6:2 FTS) induced cardiovascular abnormalities in zebrafish embryos and larvae showed that the acute toxicity of 6:2 FTS was lower than that of PFOS. 6:2 FTS could affect the development of zebrafish, including increasing the utilization of yolk sac and the length of the pharyngeal pouch, leading to pericardial edema and inhibiting beating of the heart. Then transgenic zebrafish CZ63 and CZ40 were used to further explore its cardiovascular toxicity. 6:2 FTS could induce vascular hyperplasia, inhibit atrial development, and reduce blood flow velocity in larvae at 72 hours postfertilization. In addition, 6:2 FTS enhanced CAT and GSH-Px activities, involved in calcium signalling and myocardial contraction, and affected MAPK, FoxO and p53 signalling pathways[3].

хранилище

2-8°C

Экологические соображения

Regulatory efforts are underway to limit the use of some Fluorinated additive material, mainly perfluorinated compounds (PFCs), due to concerns over their environmental persistency, bioaccumulation ability, and toxicity. Among the PFCs, perfluorosulfonates (PFSAs) and perfluorocarboxylates (PFCAs) are most widely detected in human and other biological samples, including those in pristine areas such as the Arctic. The longer-chained PFCs are known to be bioaccumulative and have toxic effects on biota. For example, neuroendocrine effects and peroxisome proliferation have been shown to occur. The perfluorinated sulfonamides are neutral compounds and are consequently not as water-soluble as the acids and are more volatile. It has been suggested that they are transformed into perfluorinated sulfonates (PFSAs) and PFCAs in the atmosphere. Since the perfluorinated acids have high water solubilities and low pKa values, they are dissociated at environmentally relevant pH values. They are primarily found in water or bound to particles, sediments, and soils[1-2].

1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота препаратная продукция и сырье

сырьё

препарат


1H, 1H, 2H, 2H-ПЕРФТОРОКТАНСульфоновая кислота поставщик

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