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SILICA

 структура
14464-46-1
CAS №
14464-46-1
английское имя:
SILICA
Синонимы:
SIO2;KIESELGUHR;SILICON OXIDE;SAND;QUARTZ SAND;SILICA GEL 60;CRISTOBALITE;SILICA SAND;SILICON (IV) OXIDE;DESICCANT
CBNumber:
CB5199387
Формула:
O2Si
молекулярный вес:
60.08
MOL File:
14464-46-1.mol

SILICA атрибут

Температура плавления: 1610 °C(lit.)
Температура кипения: >100 °C(lit.)
плотность: 2.6 g/mL at 25 °C(lit.)
показатель преломления: n20/D 1.544(lit.)
температура хранения: 2-8°C
растворимость: insoluble in H2O, acid solutions; soluble in HF
форма: таблетки (~0,5 г каждая)
цвет: colorless hexagonal, hexane crystals, crystalline
crystal system: square
Space group: P42212
Lattice constant:
a/nmb/nmc/nmα/oβ/oγ/oV/nm3
0.4980.4980.6949090900.1721
ИнЧИКей: VYPSYNLAJGMNEJ-UHFFFAOYSA-N
Предложение 65 Список: Silica, crystalline (airborne particles of respirable size)
Система регистрации веществ EPA: Cristobalite (14464-46-1)
безопасность
  • Заявления о рисках и безопасности
  • код информации об опасности(GHS)
Коды опасности Xn,T
Заявления о рисках 48/20
Заявления о безопасности 22
OEB D
OEL TWA: 0.05 mg/m3
WGK Германия 3
RTECS VV7340000
F 3
кода HS 28112290
Токсичность TCLo inhalation in human: 16mppcf/8H/17
символ(GHS) GHS hazard pictograms
сигнальное слово Danger
Заявление об опасности
пароль Заявление об опасности Класс опасности категория сигнальное слово пиктограмма предупреждение
H372 Поражает органы в результате многократного или продолжительного воздействия. Специфическая органная токсичность, многократное воздействие Категория 1 Опасность GHS hazard pictograms P260, P264, P270, P314, P501
Внимание
P260 Не вдыхать газ/ пары/ пыль/ аэрозоли/ дым/ туман.
P264 После работы тщательно вымыть кожу.
P270 При использовании продукции не курить, не пить, не принимать пищу.
P314 В случае плохого самочувствия обратиться к врачу.
P501 Удалить содержимое/ контейнер на утвержденных станциях утилизации отходов.

SILICA химические свойства, назначение, производство

Химические свойства

Silicon dioxide/crystalline silica is a component of many mineral dusts and materials which melts to a glass at very high temperature.

Использование

Because of its unique physical and chemical properties, crystalline silica has many uses. Commercially produced silica products include quartzite, tripoli, ganister, chert, and novaculite. Crystalline silica also occurs in nature as agate, amethyst, chalcedony, cristobalite, flint, quartz, tridymite, and, in its most common form, sand (IARC 1997). Naturally occurring silica materials are classified by end use or industry. Sand and gravel are produced almost exclusively for road building and concrete construction, depending on particle size and shape, surface texture, and porosity (IARC 1987).

Определение

A hygroscopic substance such as activated alumina, calcium chloride, silica gel, or zinc chloride. Such substances adsorb water vapor from the air and are used to maintain a dry atmosphere in containers for food packaging, chemical reagents, etc.

Общее описание

Rounded silica sand is the naturally occurring sand usually mined from glacial deposits, sometimes called Ottawa sands. Silica sand is essentially made of quartz (SiO2 ) grains.
Pressure range: 28 < σc < 35 MPa (4 < σc < 5 ksi)
Advantages: Low cost, low density, wide availability, and excellent chemical resistance in acidic media except those containing free HF
Drawbacks: Low permeability, low crushing strength, and poor resistance to flow back

Профиль безопасности

Confirmed carcinogen with experimental carcinogenic and tumorigenic data. Poison by intratracheal route. An inhalation hazard. Human systemic effects by inhalation: cough, dyspnea, fibrosis. About twice as toxic as silica in causing sihcosis. See also other sdica entries

Возможный контакт

Cristobalite is used in the manufacture of water glass, refractories, abrasives, ceramics and enamels. Quartz is used as a mineral, natural or synthetic fiber. Tridymite is used as a filtering and insulating media and as a refractory material for furnace linings. Workers are potentially exposed to crystalline silica in such industries as granite quarrying and cutting, foundry operations; metal, coal, dentistry, painting, and nonmetallic mining; and manufacture of clay and glass products.

Канцерогенность

Respirable crystalline silica, primarily quartz dusts occurring in industrial and occupational settings, is known to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in humans. Respirable crystalline silica was first listed in the Sixth Annual Report on Carcinogens in 1991 as reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals; the listing was revised to known to be a human carcinogen in the Ninth Report on Carcinogens in 2000.

Несовместимости

Violent reactions with powerful oxidizers: fluorine, chlorine trifluoride; manganese trioxide; oxygen difluoride, hydrogen peroxide, etc.; acetylene; ammonia.

Утилизация отходов

Sanitary landfill

SILICA препаратная продукция и сырье

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SILICA поставщик

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