н-Додекан химические свойства, назначение, производство
Химические свойства
Dodecane, C12H26, is a flammable, colorless liquid with
specific gravity 0.749. It occurs in the paraffin fraction of
petroleum. Dodecane is released to the environment by
wastewater and spills from laboratory and general use of
paraffins, petroleum oils, and tars.
Физические свойства
Clear, colorless liquid with a mild aliphatic hydrocarbon odor. An odor threshold concentration of
620 ppbv was reported by Nagata and Takeuchi (1990).
Использование
Dodecane is a component of
gasoline and is used as solvent, in organic synthesis, in jet
fuel research, as a distillation chaser, and in the rubber and
paper processing industries.
Определение
ChEBI: A straight-chain alkane with 12 carbon atoms. It has been form the essential oils of various plants including Zingiber officinale (ginger).
Методы производства
Dodecane is isolated from the kerosene and gas oil fractions
of crude oil by selective adsorption and subsequent desorption
to yield mixtures of paraffins that can be separated by
fractional distillation.
Общее описание
Clear colorless liquid.
Реакции воздуха и воды
Flammable. Insoluble in water.
Профиль реактивности
Saturated aliphatic hydrocarbons, such as Dodecane, may be incompatible with strong oxidizing agents like nitric acid. Charring of the hydrocarbon may occur followed by ignition of unreacted hydrocarbon and other nearby combustibles. In other settings, aliphatic saturated hydrocarbons are mostly unreactive. They are not affected by aqueous solutions of acids, alkalis, most oxidizing agents, and most reducing agents. When heated sufficiently or when ignited in the presence of air, oxygen or strong oxidizing agents, they burn exothermically to produce carbon dioxide and water.
Пожароопасность
Dodecane is combustible.
Канцерогенность
Dodecane has been shown to be
a promoter of skin carcinogenesis for benzo[a]pyrene and
ultraviolet radiation.
Экологическая судьба
Biological. Dodecane may biodegrade in two ways. The first is the formation of dodecyl
hydroperoxide which decomposes to 1-dodecanol. The alcohol is oxidized forming dodecanoic
acid. The other pathway involves dehydrogenation to 1-dodecene, which may react with water,
giving 1-dodecanol (Dugan, 1972).
Estimated half-lives of dodecane (0.3 μg/L) from an experimental marine mesocosm during the
spring (8–16 °C), summer (20–22 °C), and winter (3–7 °C) were 1.1, 0.7, and 3.6 d, respectively
(Wakeham et al., 1983).
Chemical/Physical. Complete combustion in air yields carbon dioxide and water. Dodecane will
not hydrolyze because it has no hydrolyzable functional group.
Методы очистки
Pass it through a column of Linde type 13X molecular sieves. Store it in contact with, and distil it from sodium. Pass through a column of activated silica gel. It has been crystallised from diethyl ether at -60o. Unsaturated dry material which remained after passage through silica gel has been removed by catalytic hydrogenation (Pt2O) at 45lb/in2 (3.06 atmospheres), followed by fractional distillation under reduced pressure [Zook & Goldey J Am Chem Soc 75 3975 1953]. It has also purified by partial crystallisation from the melt. [Beilstein 1 IV 498.]
н-Додекан препаратная продукция и сырье
сырьё
препарат