Acute toxicity - Category 3, Oral
Acute toxicity - Category 3, Dermal
Acute toxicity - Category 3, Inhalation
Danger
H301 Toxic if swallowed
H311 Toxic in contact with skin
H331 Toxic if inhaled
P264 Wash ... thoroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P280 Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P271 Use only outdoors or in a well-ventilated area.
P301+P316 IF SWALLOWED: Get emergency medical help immediately.
P321 Specific treatment (see ... on this label).
P330 Rinse mouth.
P302+P352 IF ON SKIN: Wash with plenty of water/...
P316 Get emergency medical help immediately.
P361+P364 Take off immediately all contaminated clothing and wash it before reuse.
P304+P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal.
no data available
Fresh air, rest. Half-upright position. Refer for medical attention.
Remove contaminated clothes. Rinse and then wash skin with water and soap.
First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.
Rinse mouth. Rinse mouth. Refer for medical attention .
High concentrations cause lacrimation, increased nasal secretions, coughing, pulmonary rales, and weakness in animals. No human experience is reported. (USCG, 1999)
4. 4= very toxic: probable oral lethal dose (human) 50-500 mg/kg, between 1 teaspoonful & 1 oz for 70 kg person (150 lb).
Gc/ms analyses of profiles of volatile constituents obtained from cord blood & maternal blood samples reflect transplacentally acquired halogenated hydrocarbons & accum in fetal cord blood.
If material on fire or involved in fire: Do not extinguish fire unless flow can be stopped. Extinguish fire using agent suitable for type of surrounding fire. (Material itself does not burn or burns with difficulty.) Use water if flooding quantities as fog. Cool all affected containers with flooding quantities of water. Apply water from as far a distance as possible. Use foam, dry chemical, or carbon dioxide. Keep run-off water out of sewers and water sources.
Special Hazards of Combustion Products: Toxic gases and vapors, such as nitrogen oxides, hydrogen chloride, and carbon monoxide, may be released in a fire. (USCG, 1999)
Use water spray, foam, powder, carbon dioxide. In case of fire: keep drums, etc., cool by spraying with water.
HEALTH | 2 | Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury (e.g. diethyl ether, ammonium phosphate, iodine) | |
FIRE | 2 | Must be moderately heated or exposed to relatively high ambient temperature before ignition can occur and multiple finely divided suspended solids that do not require heating before ignition can occur. Flash point between 37.8 and 93.3 °C (100 and 200 °F). (e.g. diesel fuel, sulfur) | |
REACT | 3 | Capable of detonation or explosive decomposition but requires a strong initiating source, must be heated under confinement before initiation, reacts explosively with water, or will detonate if severely shocked (e.g. ammonium nitrate, cesium, hydrogen peroxide) | |
SPEC. HAZ. |
Personal protection: self-contained breathing apparatus. Collect leaking liquid in sealable metal containers.
Personal protection: self-contained breathing apparatus. Collect leaking liquid in sealable metal containers.
1. Remove all ignition sources. 2. Ventilate area of spill or leak. 3. For small quantities, absorb on paper towels. Evaporate in safe place (such as a fume hood). Allow sufficient time for evaporating vapors to completely clear the hood ductwork. Burn the paper in a suitable location away from combustible materials. Large quantities can be collected & atomized in a suitable combustion chamber equipped with an appropriate effluent gas cleaning device. 1,1-Dichloro-1-nitroethane should not be allowed to enter a confined space, such as a sewer, because of the possibility of an explosion.
NO open flames, NO sparks and NO smoking. Above 57.8°C use a closed system, ventilation and explosion-proof electrical equipment. Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam.
Fireproof. Separated from strong oxidants and food and feedstuffs.IN GENERAL, MATERIALS WHICH ARE TOXIC AS STORED OR WHICH CAN DECOMP INTO TOXIC COMPONENTS...SHOULD BE STORED IN A COOL, WELL-VENTILATED PLACE, OUT OF DIRECT RAYS OF THE SUN, AWAY FROM AREAS OF HIGH FIRE HAZARD, & SHOULD BE PERIODICALLY INSPECTED... INCOMPATIBLE MATERIALS SHOULD BE ISOLATED FROM EACH OTHER.
TLV: 2 ppm as TWA
no data available
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the risk-elimination area.
Wear safety goggles.
Protective gloves.
Use ventilation, local exhaust or breathing protection.
no data available
COLORLESS LIQUID
Unpleasant odor.
no data available
123.5°C at 760 mmHg
Class II Combustible Liquid: Fl.P. at or above 100°F and below 140°F.
no data available
31.7°C
no data available
no data available
no data available
no data available
1 to 10 mg/mL at 66° F (NTP, 1992)
1.56
16 mm Hg at 77° F (NTP, 1992)
1.481 g/cm3
5 (NTP, 1992) (Relative to Air)
no data available
On combustion, forms toxic gases including hydrogen chloride, nitrogen oxides and phosgene. Reacts violently with strong oxidants. Attacks rubber and some forms of plastic.
no data available
MODERATE WHEN EXPOSED TO HEAT OR FLAME.1,1-DICHLORO-1-NITROETHANE is incompatible with oxidizers. It will attack some forms of plastics, rubber and coatings. (NTP, 1992)
no data available
Strong oxidizers (Note: Corrosive to iron in presence of moisture).
no data available
no data available
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The substance is irritating to the eyes, skin and respiratory tract. Inhalation of the vapour may cause lung oedema. See Notes.
no data available
A harmful contamination of the air will be reached quickly on evaporation of this substance at 20°C; on spraying or dispersing, however, much faster.
no data available
Based upon an estimated water solubility of 2500 mg/l(2), the BCF of 1,1-dichloro-1- nitroethane can be estimated to be approximately 7.5 from a regression-derived equation(1). This estimated BCF value suggests that bioconcentration in aquatic organisms may not be an important fate process(SRC).
Using a structure estimation method based on molecular connectivity indexes(1), the Koc for 1,1-dichloro-1-nitroethane can be estimated to be about 36(SRC). The Koc for 1,1-dichloro-1-nitroethane can be estimated to be about 59(SRC) based on an estimated water solubility of 2500 mg/L(4) and a regression derived equation(2). According to a suggested classification scheme(3), these estimated Koc values suggest that 1,1-dichloro-1-nitroethane has high to very high soil mobility(SRC).
no data available
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials.
ADR/RID: UN2650 (For reference only, please check.)
IMDG: UN2650 (For reference only, please check.)
IATA: UN2650 (For reference only, please check.)
ADR/RID: 1,1-DICHLORO-1- NITROETHANE (For reference only, please check.)
IMDG: 1,1-DICHLORO-1- NITROETHANE (For reference only, please check.)
IATA: 1,1-DICHLORO-1- NITROETHANE (For reference only, please check.)
ADR/RID: 6.1 (For reference only, please check.)
IMDG: 6.1 (For reference only, please check.)
IATA: 6.1 (For reference only, please check.)
ADR/RID: II (For reference only, please check.)
IMDG: II (For reference only, please check.)
IATA: II (For reference only, please check.)
ADR/RID: No
IMDG: No
IATA: No
no data available
no data available
The symptoms of lung oedema often do not become manifest until a few hours have passed and they are aggravated by physical effort.Rest and medical observation is therefore essential.
The information in this MSDS is only applicable to the specified product, unless otherwise specified, it is not applicable to the mixture of this product and other substances. This MSDS only provides information on the safety of the product for those who have received the appropriate professional training for the user of the product. Users of this MSDS must make independent judgments on the applicability of this SDS. The authors of this MSDS will not be held responsible for any harm caused by the use of this MSDS.