NICKEL COBALT OXIDE

Nickel/nickel oxides Cobalt/cobalt oxides

Wear self-contained breathing apparatus for firefighting if necessary.

No data available

Wear respiratory protection. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Evacuate personnel to safe areas. Avoid breathing dust.

For personal protection see section 8.

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

For disposal see section 13.

Advice on safe handling

Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Advice on safe

handling

Avoid exposure - obtain special instructions before use.

Advice on protection against fire and explosion

Provide appropriate exhaust ventilation at places where dust is formed.

Hygiene measures

Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product.

For precautions see section 2.2.

Storage conditions

Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

The selected protective gloves have to satisfy the specifications of Regulation (EU) 2016/425 and the standard EN 374 derived from it.

Full contact

Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

Splash contact Material: Nitrile rubber

Minimum layer thickness: 0,11 mm Break through time: 480 min

Material tested:Dermatril? (KCL 740 / Aldrich Z677272, Size M)

data source: KCL GmbH, D-36124 Eichenzell, phone +49 (0)6659 87300, e-mail sales@kcl.de, test method: EN374

If used in solution, or mixed with other substances, and under conditions which differ from EN 374, contact the supplier of the EC approved gloves. This recommendation is advisory only and must be evaluated by an industrial hygienist and safety officer familiar with the specific situation of anticipated use by our customers. It should not be construed as offering an approval for any specific use scenario.

Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

Where risk assessment shows air-purifying respirators are appropriate use a full- face particle respirator type N100 (US) or type P3 (EN 143) respirator cartridges as a backup to engineering controls. If the respirator is the sole means of protection, use a full-face supplied air respirator. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

Prevent further leakage or spillage if safe to do so. Do not let product enter drains. Discharge into the environment must be avoided.

No data available

No data available

Stable under recommended storage conditions.

No data available

No data available

Strong oxidizing agents, Strong acids

In the event of fire: see section 5

Mixture

No data available

No data available

No data available

No data available

This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

Very toxic to aquatic life with long lasting effects.

Components Nickel oxide

Toxicity to fish semi-static test LC50 - Oncorhynchus mykiss (rainbow trout) - 15,3 mg/l - 96 h

Remarks: (ECHA)

Toxicity to daphnia and other aquatic invertebrates

static test LC50 - Ceriodaphnia dubia (water flea) - 0,027 mg/l

- 48 h

Remarks: (ECHA)

Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 0,081 - 0,148 mg/l - 72 h

(OECD Test Guideline 201)

Toxicity to bacteria EC50 - activated sludge - 33 mg/l - 30 min

(ISO 8192)

Cobalt(II) oxide

Toxicity to fish semi-static test LC50 - Pimephales promelas (fathead minnow)

- 1,86 mg/l - 96 h (US-EPA)

Toxicity to daphnia and other aquatic invertebrates

static test LC50 - Ceriodaphnia dubia (water flea) - 136 mg/l - 48 h

(US-EPA)

Toxicity to algae static test ErC50 - Pseudokirchneriella subcapitata - 0,095 mg/l

- 72 h

(OECD Test Guideline 201)

Toxicity to bacteria static test EC50 - activated sludge - 120 mg/l - 0,5 h

(OECD Test Guideline 209)

Product

Offer surplus and non-recyclable solutions to a licensed disposal company. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber.

Contaminated packaging

Dispose of as unused product.

ADR/RID: 3077 IMDG: 3077 IATA: 3077

ADR/RID: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Nickel oxide,

Cobalt(II) oxide)

IMDG: ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S. (Cobalt(II) oxide,

Nickel oxide)

IATA: Environmentally hazardous substance, solid, n.o.s. (Cobalt(II) oxide, Nickel oxide)

ADR/RID: 9 IMDG: 9 IATA: 9

ADR/RID: III IMDG: III IATA: III

ADR/RID: yes IMDG Marine pollutant: yes IATA: yes

Further information

EHS-Mark required (ADR 2.2.9.1.10, IMDG code 2.10.3) for single packagings and combination packagings containing inner packagings with Dangerous Goods > 5L for liquids or > 5kg for solids.Packages smaller than or equal to 5 kg / L , not dangerous goods of Class 9

This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.

Authorisations and/or restrictions on use

REACH - Restrictions on the manufacture, placing on the market and use of certain dangerous substances, preparations and articles (Annex XVII)

National legislation

Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances.

: Nickel oxide

: ACUTE TOXIC

: ENVIRONMENTAL HAZARDS

For this product a chemical safety assessment was not carried out

Full text of H-Statements referred to under sections 2 and 3.

H301 Toxic if swallowed.

H317 May cause an allergic skin reaction.

H330 Fatal if inhaled.

H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled. H350i May cause cancer by inhalation.

H372 Causes damage to organs through prolonged or repeated exposure. H400 Very toxic to aquatic life.

H410 Very toxic to aquatic life with long lasting effects. H413 May cause long lasting harmful effects to aquatic life.