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ChemicalBook >> CAS DataBase List >> Boron trifluoride diethyl etherate

Boron trifluoride diethyl etherate

Boron trifluoride diethyl etherate price.
  • $10.6 - $1560
  • Product name: Boron trifluoride diethyl etherate
  • CAS: 109-63-7
  • MF: C4H10BF3O
  • MW: 141.93
  • EINECS:203-689-8
  • MDL Number:MFCD00013194
  • Synonyms:ether,diethyl,borofluoride ;Ethyl ether, compd. with boron fluoride (BF3 1:1);ethylether,cmpdwithboronfluoride(bf3)(1:1) ;trifluoroboranediethyletherate ;trifluoroboron-diethylethercomplex ;Boron trifluoride diethyl etherate, 46.5% BF{3} min, packaged under Argon in resealable ChemSeal^t b;Boron trifluoride diethyl etherate, 46.5% BF3 min, packaged under Argon in resealable ChemSealTM bottles;Ethoxy-ethanetrifluoroborane
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  • Alfa Aesar
  • Atlantic Research Chemicals
  • Biosynth Carbosynth
  • BroadPharm
  • Chem-Impex
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  • Strem Chemicals
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  • TCI Chemical
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  • ManufacturerAlfa Aesar
  • Product numberA15275
  • Product descriptionBoron trifluoride diethyl etherate, 98+%
  • Packaging100ml
  • Price$40.9
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number041796
  • Product descriptionBoron trifluoride diethyl etherate, 46.5% BF3 min, packaged under Argon in resealable ChemSeal? bottles
  • Packaging100g
  • Price$45.8
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product number041796
  • Product descriptionBoron trifluoride diethyl etherate, 46.5% BF3 min, packaged under Argon in resealable ChemSeal? bottles
  • Packaging500g
  • Price$66.8
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA15275
  • Product descriptionBoron trifluoride diethyl etherate, 98+%
  • Packaging500ml
  • Price$71
  • Updated2024-03-01
  • Buy
  • ManufacturerAlfa Aesar
  • Product numberA15275
  • Product descriptionBoron trifluoride diethyl etherate, 98+%
  • Packaging1000ml
  • Price$117
  • Updated2024-03-01
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  • ManufacturerAtlantic Research Chemicals
  • Product numberXS101316
  • Product descriptionBoron trifluoride diethyl etherate 95%
  • Packaging1gm:
  • Price$10.6
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB29693
  • Product descriptionBoron trifluoride etherate
  • Packaging25g
  • Price$75
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB29693
  • Product descriptionBoron trifluoride etherate
  • Packaging50g
  • Price$85
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB29693
  • Product descriptionBoron trifluoride etherate
  • Packaging100g
  • Price$100
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB29693
  • Product descriptionBoron trifluoride etherate
  • Packaging500g
  • Price$165
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB29693
  • Product descriptionBoron trifluoride etherate
  • Packaging250g
  • Price$200
  • Updated2021-12-16
  • Buy
  • ManufacturerBroadPharm
  • Product numberBP-21037
  • Product descriptionBoron trifluoride diethyl etherate 98%
  • Packaging100mL
  • Price$54
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number06933
  • Product descriptionBorontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration)
  • Packaging100ML
  • Price$25.76
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number06933
  • Product descriptionBorontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration)
  • Packaging2.5L
  • Price$72.5
  • Updated2021-12-16
  • Buy
  • ManufacturerChem-Impex
  • Product number06933
  • Product descriptionBorontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration)
  • Packaging5L
  • Price$124
  • Updated2021-12-16
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  • ManufacturerChem-Impex
  • Product number06933
  • Product descriptionBorontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration)
  • Packaging1L
  • Price$132.16
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
Alfa Aesar A15275 Boron trifluoride diethyl etherate, 98+% 100ml $40.9 2024-03-01 Buy
Alfa Aesar 041796 Boron trifluoride diethyl etherate, 46.5% BF3 min, packaged under Argon in resealable ChemSeal? bottles 100g $45.8 2024-03-01 Buy
Alfa Aesar 041796 Boron trifluoride diethyl etherate, 46.5% BF3 min, packaged under Argon in resealable ChemSeal? bottles 500g $66.8 2024-03-01 Buy
Alfa Aesar A15275 Boron trifluoride diethyl etherate, 98+% 500ml $71 2024-03-01 Buy
Alfa Aesar A15275 Boron trifluoride diethyl etherate, 98+% 1000ml $117 2024-03-01 Buy
Atlantic Research Chemicals XS101316 Boron trifluoride diethyl etherate 95% 1gm: $10.6 2021-12-16 Buy
Biosynth Carbosynth FB29693 Boron trifluoride etherate 25g $75 2021-12-16 Buy
Biosynth Carbosynth FB29693 Boron trifluoride etherate 50g $85 2021-12-16 Buy
Biosynth Carbosynth FB29693 Boron trifluoride etherate 100g $100 2021-12-16 Buy
Biosynth Carbosynth FB29693 Boron trifluoride etherate 500g $165 2021-12-16 Buy
Biosynth Carbosynth FB29693 Boron trifluoride etherate 250g $200 2021-12-16 Buy
BroadPharm BP-21037 Boron trifluoride diethyl etherate 98% 100mL $54 2021-12-16 Buy
Chem-Impex 06933 Borontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration) 100ML $25.76 2021-12-16 Buy
Chem-Impex 06933 Borontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration) 2.5L $72.5 2021-12-16 Buy
Chem-Impex 06933 Borontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration) 5L $124 2021-12-16 Buy
Chem-Impex 06933 Borontrifluoride-ethylethercomplex,98%(Assaybytitration) 98%(Assaybytitration) 1L $132.16 2021-12-16 Buy

Properties

Melting point :−58 °C(lit.)
Boiling point :126-129 °C(lit.)
Density :1.15 g/mL(lit.)
vapor density :4.9 (vs air)
vapor pressure :4.2 mm Hg ( 20 °C)
refractive index :n20/D 1.344(lit.)
Flash point :118 °F
storage temp. :Store below +30°C.
solubility :Miscible with ether and alcohol.
form :liquid
Specific Gravity :1.126 (20/4℃)
color :brown
explosive limit :5.1-18.2%(V)
Water Solubility :Reacts
Sensitive :Moisture Sensitive
Hydrolytic Sensitivity :7: reacts slowly with moisture/water
Merck :14,1350
BRN :3909607
Exposure limits :ACGIH: TWA 0.1 ppm; Ceiling 0.7 ppm
Stability :Stable. Highly flammable. May form explosive peroxides in contact with air or oxygen. Reacts exothermically with water to form extremely flammable diethyl ether and toxic, corrosive boron trifluoride hydrates. Also incompatible with bases, amines, alkali metals.
InChIKey :MZTVMRUDEFSYGQ-UHFFFAOYSA-N
CAS DataBase Reference :109-63-7(CAS DataBase Reference)
NIST Chemistry Reference :Boron trifluoride etherate(109-63-7)
EPA Substance Registry System :Boron, trifluoro[1,1'-oxybis[ethane]]-, (T-4)- (109-63-7)

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H226 Flammable liquid and vapour Flammable liquids Category 3 Warning
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning GHS hazard pictograms P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger GHS hazard pictograms P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger GHS hazard pictograms P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger GHS hazard pictograms P260, P264, P270, P314, P501
H412 Harmful to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 3 P273, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Description

Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth?s atmosphere.

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