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ChemicalBook >> CAS DataBase List >> (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)

(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II) price.
  • $34.12 - $857.9
  • Product name: (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II)
  • CAS: 259259-80-8
  • MF: C32H38CoN2O4
  • MW: 573.59
  • EINECS:
  • MDL Number:MFCD06797062
  • Synonyms:(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)-1,2-DIMESITYLETHYLENEDIAMINATO COBALT(II);(S)-AMAC;Cobalt,[[3,3'-[[(1S,2S)-1,2-bis(2,4,6-triMethylphenyl)-1,2-ethanediyl]bis[(nitrilo-kN)Methylidyne]]bis[2,4-pentanedionato-kO2]](2-)]-, (SP-4-2)-;(S,S)-AMAC;(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
11 prices
Selected condition:
Brand
  • AK Scientific
  • American Custom Chemicals Corporation
  • Biosynth Carbosynth
  • Sigma-Aldrich
  • TCI Chemical
  • TRC
Package
  • 10mg
  • 25mg
  • 50mg
  • 100MG
  • 250mg
  • 500mg
  • ManufacturerAK Scientific
  • Product number4013AL
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging10mg
  • Price$139
  • Updated2021-12-16
  • Buy
  • ManufacturerAmerican Custom Chemicals Corporation
  • Product numberOGM0000052
  • Product description(1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)- 1,2-DIMESITYLETHYLENEDIAMINATO COBALT (II) 95.00%
  • Packaging100MG
  • Price$857.9
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB59945
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging10mg
  • Price$66
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB59945
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging25mg
  • Price$127.5
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB59945
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging50mg
  • Price$195
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB59945
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging100mg
  • Price$300
  • Updated2021-12-16
  • Buy
  • ManufacturerBiosynth Carbosynth
  • Product numberFB59945
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging250mg
  • Price$675
  • Updated2021-12-16
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number708844
  • Product description(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
  • Packaging100mg
  • Price$34.12
  • Updated2024-03-01
  • Buy
  • ManufacturerSigma-Aldrich
  • Product number708844
  • Product description(1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II)
  • Packaging500mg
  • Price$389
  • Updated2023-06-20
  • Buy
  • ManufacturerTCI Chemical
  • Product numberB2315
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging100mg
  • Price$303
  • Updated2024-03-01
  • Buy
  • ManufacturerTRC
  • Product numberA165435
  • Product description(1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II)
  • Packaging10mg
  • Price$65
  • Updated2021-12-16
  • Buy
Manufacturer Product number Product description Packaging Price Updated Buy
AK Scientific 4013AL (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 10mg $139 2021-12-16 Buy
American Custom Chemicals Corporation OGM0000052 (1S,2S)-N,N'-BIS(2-ACETYL-3-OXO-2-BUTENYLIDENE)- 1,2-DIMESITYLETHYLENEDIAMINATO COBALT (II) 95.00% 100MG $857.9 2021-12-16 Buy
Biosynth Carbosynth FB59945 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 10mg $66 2021-12-16 Buy
Biosynth Carbosynth FB59945 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 25mg $127.5 2021-12-16 Buy
Biosynth Carbosynth FB59945 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 50mg $195 2021-12-16 Buy
Biosynth Carbosynth FB59945 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 100mg $300 2021-12-16 Buy
Biosynth Carbosynth FB59945 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 250mg $675 2021-12-16 Buy
Sigma-Aldrich 708844 (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) 100mg $34.12 2024-03-01 Buy
Sigma-Aldrich 708844 (1S,2S)-N,N′-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato cobalt(II) 500mg $389 2023-06-20 Buy
TCI Chemical B2315 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 100mg $303 2024-03-01 Buy
TRC A165435 (1S,2S)-N,N'-Bis(2-acetyl-3-oxo-2-butenylidene)-1,2-dimesitylethylenediaminato Cobalt(II) 10mg $65 2021-12-16 Buy

Properties

Melting point :242-246°C
storage temp. :under inert gas (nitrogen or Argon) at 2-8°C
form :powder to crystal
color :Orange to Brown
optical activity :[α]/D 309°, c = 0.1 in chloroform

Safety Information

Symbol(GHS): GHS hazard pictogramsGHS hazard pictograms
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning GHS hazard pictograms P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning GHS hazard pictograms P264, P280, P305+P351+P338,P337+P313P
H351 Suspected of causing cancer Carcinogenicity Category 2 Warning P201, P202, P281, P308+P313, P405,P501
Precautionary statements:
P201 Obtain special instructions before use.
P202 Do not handle until all safety precautions have been read and understood.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P308+P313 IF exposed or concerned: Get medical advice/attention.
P405 Store locked up.
P501 Dispose of contents/container to..…

Description

Catalyst for:
  • Stereoselective preparation of benzylic alcohols via oxidative kinetic resolution of secondary benzylic alcohols with oxygen in presence of alkene
  • Enantioselective borohydride reduction
  • Preparation of ?-nitro alcohols from aldehydes and nitroalkanes by stereoselective Henry reaction in presence of amine bases
  • Preparation of optically pure diarylpropanediols via reduction of the corresponding diketones

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