DIISOPROPYLSILYL BIS(TRIFLUOROMETHANESULFONATE)
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- $70 - $875
- Product name: DIISOPROPYLSILYL BIS(TRIFLUOROMETHANESULFONATE)
- CAS: 85272-30-6
- MF: C8H14F6O6S2Si
- MW: 412.4
- EINECS:
- MDL Number:MFCD00043111
- Synonyms:DIISOPROPYLSILYL BIS(TRIFLUOROMETHANESULFONATE);TRIFLUOROMETHANESULFONIC ACID DIISOPROPYLSILYLENE ESTER;DIISOPROPYLSILYL BIS(TRIFLUOROMETHANE-SU LFONATE), TECH.;diisopropylbis(trifluoromethanesulfonyl)silane;Bis(trifluoromethanesulfonic acid)diisopropylsilanediyl ester;Diisopropylsilylenebis(trifluoromethanesulfonate);Methanesulfonic acid, trifluoro-, bis(1-methylethyl)silylene ester;Methanesulfonic acid, 1,1,1-trifluoro-, bis(1-methylethyl)[[(trifluoromethyl)sulfonyl]oxy]silyl ester
7 prices
Selected condition：
Brand
- Biosynth Carbosynth
- Sigma-Aldrich
Package
- 1g
- 2g
- 5G
- 10g
- 25g
- ManufacturerBiosynth Carbosynth
- Product numberFD90402
- Product descriptionDiisopropylsilyl Bis(Trifluoromethanesulfonate)
- Packaging1g
- Price$70
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFD90402
- Product descriptionDiisopropylsilyl Bis(Trifluoromethanesulfonate)
- Packaging2g
- Price$120
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFD90402
- Product descriptionDiisopropylsilyl Bis(Trifluoromethanesulfonate)
- Packaging5G
- Price$250
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFD90402
- Product descriptionDiisopropylsilyl Bis(Trifluoromethanesulfonate)
- Packaging10g
- Price$400
- Updated2021-12-16
- Buy
- ManufacturerBiosynth Carbosynth
- Product numberFD90402
- Product descriptionDiisopropylsilyl Bis(Trifluoromethanesulfonate)
- Packaging25g
- Price$875
- Updated2021-12-16
- Buy
- ManufacturerSigma-Aldrich
- Product number375942
- Product descriptionDiisopropylsilyl bis(trifluoromethanesulfonate) 96%
- Packaging5g
- Price$123
- Updated2024-03-01
- Buy
- ManufacturerSigma-Aldrich
- Product number375942
- Product descriptionDiisopropylsilyl bis(trifluoromethanesulfonate) 96%
- Packaging25g
- Price$559
- Updated2023-06-20
- Buy
| Manufacturer | Product number | Product description | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|
| Biosynth Carbosynth | FD90402 | Diisopropylsilyl Bis(Trifluoromethanesulfonate) | 1g | $70 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD90402 | Diisopropylsilyl Bis(Trifluoromethanesulfonate) | 2g | $120 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD90402 | Diisopropylsilyl Bis(Trifluoromethanesulfonate) | 5G | $250 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD90402 | Diisopropylsilyl Bis(Trifluoromethanesulfonate) | 10g | $400 | 2021-12-16 | Buy |
| Biosynth Carbosynth | FD90402 | Diisopropylsilyl Bis(Trifluoromethanesulfonate) | 25g | $875 | 2021-12-16 | Buy |
| Sigma-Aldrich | 375942 | Diisopropylsilyl bis(trifluoromethanesulfonate) 96% | 5g | $123 | 2024-03-01 | Buy |
| Sigma-Aldrich | 375942 | Diisopropylsilyl bis(trifluoromethanesulfonate) 96% | 25g | $559 | 2023-06-20 | Buy |
Properties
Boiling point :85-86 °C2 mm Hg(lit.)
Density :1.396 g/mL at 25 °C(lit.)
refractive index :n20/D 1.382(lit.)
Flash point :>230 °F
Specific Gravity :1.396
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :3567500
Density :1.396 g/mL at 25 °C(lit.)
refractive index :n
Flash point :>230 °F
Specific Gravity :1.396
Hydrolytic Sensitivity :8: reacts rapidly with moisture, water, protic solvents
BRN :3567500
Safety Information
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Description
Diisopropylsilyl bis(trifluoromethanesulfonate) has more recently been used to prepare diisopropylsilyl-linked oligonucleotide analogs. Silylation of 5'-O-(dimethoxytrityl)-2'-deoxynucleosides using diisopropylsilyl bis(trifluoromethanesulfonate) and the hindered base 2,6-di-t-butyl-4-methylpyridine (Dtbp) provided quantitative yield of 3'-O-diisopropylsilanols (eq 2). Hence, silylation of 5'-O-(dimethoxytrityl)thymidine, N6-benzoyl-2'-deoxy-5'-O- (dimethoxytrityl)adenosine, N4-benzoyl-2'-deoxy-5'-O-(dimethoxytrityl) cytidine, and N2-isobutyryl-2'-deoxy-5'-O-(dimethoxytrityl) guanosine gave the desired products 5a–d in excellent yields.Coupling of products 5a–d with unprotected thymidine resulted in formation of 3',5'-linked dinucleosides 6a–d selectively, and the dimer 7 from reaction with secondary hydroxyl group of thymidine was not observed (eq 3). Subsequent silylation and coupling with another molecule of thymidine gave 3,5- linked trinucleoside 8 in 76% yield (eq 4). A tetrathymidylate oligomer was prepared by 3'-O-silylation of 8 followed by coupling with thymidine. Although no self-condensation was observed, only 30% of the product 9 was obtained after purification by preparative HPLC.
Related product price
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