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ChemicalBook >> CAS DataBase List >> Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea

Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea

$116 - $1320
Product name: Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea
CAS: 852913-16-7
MF: C29H28F6N4OS
MW: 594.61
EINECS:
MDL Number:MFCD16875670
Synonyms:N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8a,9S)-6'-methoxy-9-cinchonanyl]thiourea;N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8a,9S)-6'-methoxy-9-cinchonanyl]thiourea 90%; 1-[3,5-BIS(TRIFLUOROMETHYL)PHENYL]-3-[(S)(6-METHOXY-4-QUINOLINYL)-[(2S,4S,5R)-5-VINYL-1-AZA-BICYCLO[2.2.2]OCT-2-YL]METHYL]THIOUREA;1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea;N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methox ycinchonan-9-yl]thiourea,99%d.e.;1-(3,5-Bis(trifluoromethyl)phenyl)-3-((6-methoxyquinolin-4-yl)((1S,2R,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea;Epi-N-Quinyl-N’-bis(3,5-trifluoromethyl) phenylthiourea;N-[3,5-bis(trifluoroMethyl)phenyl]-N'-[(8α,9S)-6'-Methoxycinchonan-9-yl]- Thiourea

Price11 Properties Safety Information Description

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ACHEMBLOCK
Arctom
Chemenu
ChemScene
Crysdot
Sigma-Aldrich

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50mg
100mg
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ManufacturerACHEMBLOCK
Product numberL14770
Product description1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%
Packaging250MG
Price$175
Updated2021-12-16
Buy

ManufacturerACHEMBLOCK
Product numberL14770
Product description1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%
Packaging500MG
Price$335
Updated2021-12-16
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ManufacturerArctom
Product numberAS613938
Product description1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 98%
Packaging100mg
Price$283
Updated2021-12-16
Buy

ManufacturerArctom
Product numberAS613938
Product description1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 98%
Packaging250mg
Price$424
Updated2021-12-16
Buy

ManufacturerArctom
Product numberAS613938
Product description1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 98%
Packaging1g
Price$1057
Updated2021-12-16
Buy

ManufacturerChemenu
Product numberCM104643
Product description1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%
Packaging1g
Price$440
Updated2021-12-16
Buy

ManufacturerChemenu
Product numberCM104643
Product description1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%
Packaging5g
Price$1320
Updated2021-12-16
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ManufacturerChemScene
Product numberCS-0028351
Product descriptionN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methoxycinchonan-9-yl]thiourea
Packaging50mg
Price$116
Updated2021-12-16
Buy

ManufacturerChemScene
Product numberCS-0028351
Product descriptionN-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methoxycinchonan-9-yl]thiourea
Packaging100mg
Price$172
Updated2021-12-16
Buy

ManufacturerCrysdot
Product numberCD51000302
Product description1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 97%
Packaging1g
Price$1238
Updated2021-12-16
Buy

ManufacturerSigma-Aldrich
Product number690481
Product descriptionN-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8a,9S)-6′-methoxy-9-cinchonanyl]thiourea 90%
Packaging250mg
Price$517
Updated2024-03-01
Buy

Manufacturer	Product number	Product description	Packaging	Price	Updated	Buy
ACHEMBLOCK	L14770	1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%	250MG	$175	2021-12-16	Buy
ACHEMBLOCK	L14770	1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%	500MG	$335	2021-12-16	Buy
Arctom	AS613938	1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 98%	100mg	$283	2021-12-16	Buy
Arctom	AS613938	1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 98%	250mg	$424	2021-12-16	Buy
Arctom	AS613938	1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 98%	1g	$1057	2021-12-16	Buy
Chemenu	CM104643	1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%	1g	$440	2021-12-16	Buy
Chemenu	CM104643	1-[3,5-bis(trifluoromethyl)phenyl]-3-[(S)-[(1S,2S,4S,5R)-5-ethenyl-1-azabicyclo[2.2.2]octan-2-yl](6-methoxyquinolin-4-yl)methyl]thiourea 97%	5g	$1320	2021-12-16	Buy
ChemScene	CS-0028351	N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methoxycinchonan-9-yl]thiourea	50mg	$116	2021-12-16	Buy
ChemScene	CS-0028351	N-[3,5-Bis(trifluoromethyl)phenyl]-N'-[(8α,9S)-6'-methoxycinchonan-9-yl]thiourea	100mg	$172	2021-12-16	Buy
Crysdot	CD51000302	1-(3,5-Bis(trifluoromethyl)phenyl)-3-((S)-(6-methoxyquinolin-4-yl)((1S,2S,4S,5R)-5-vinylquinuclidin-2-yl)methyl)thiourea 97%	1g	$1238	2021-12-16	Buy
Sigma-Aldrich	690481	N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8a,9S)-6′-methoxy-9-cinchonanyl]thiourea 90%	250mg	$517	2024-03-01	Buy

Properties

Boiling point :598.2±60.0 °C(Predicted)
Density :1.39±0.1 g/cm3(Predicted)
pka :11.39±0.70(Predicted)

Safety Information

Symbol(GHS):

Signal word:

Danger

Hazard statements:

Code	Hazard statements	Hazard class	Category	Signal word	Pictogram	P-Codes
H301	Toxic if swalloed	Acute toxicity,oral	Category 3	Danger		P264, P270, P301+P310, P321, P330,P405, P501

Precautionary statements:

P301+P310

IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.

Description

N-[3,5-Bis(trifluoromethyl)phenyl]-N′-[(8a,9S)-6′-methoxy-9-cinchonanyl]thiourea is a bifunctional cinchona organocatalyst, which can be used to synthesize:

Stereoselective diaryl(nitro)butanone via enantioselective Michael addition of nitromethane to chalcones.
Enantioselective β-amino acids via asymmetric Mannich reaction of malonates with aryl and alkyl imines.
The synthesis of 3-indolylmethanamines by the reaction of indoles with imines via asymmetric Friedel-Crafts reaction.
The enantioselective conjugate addition of active methylene compounds to enones to obtain the corresponding addition products.

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