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ChemicalBook CAS DataBase List 1, 2-Epoxyucyclohex-4-ene

1, 2-Epoxyucyclohex-4-ene synthesis

3synthesis methods
-

Yield:71-43-2 51 %Chromat. ,6253-27-6 49 %Chromat.

Reaction Conditions:

with [(N-benzenesulfonyl-N,N’-bis(2-pyridylmethyl)-1,2-cyclohexanediamine)-diacetonitrilocobalt(II)] perchlorate;3-chloro-benzenecarboperoxoic acid in acetonitrile at 24.84; for 0.5 h;Catalytic behavior;Reagent/catalyst;

Steps:

Reactivity

General procedure: Unless stated otherwise, all reactivity studies were done at 298 K in MeCN under air. The yields of organic products were determined by GC; all reported values are the average of the measurements for at least three independent reactions. The listed errors represent one standard deviation. The identities and yields of products were confirmed by comparing the GC retention times with those of authentic compounds and by comparing the peak integrations with that of a non-reactive 1,2-dichlorobenzene internal standard

References:

Bell-Taylor, Angela;Gorden, John D.;Hardy, Emily E.;Goldsmith, Christian R. [Inorganica Chimica Acta,2018,vol. 482,p. 206 - 212]