![](/CAS/GIF/18226-42-1.gif)
1,3,5-Tris(bromomethyl)benzene synthesis
- Product Name:1,3,5-Tris(bromomethyl)benzene
- CAS Number:18226-42-1
- Molecular formula:C9H9Br3
- Molecular Weight:356.88
![Mesitylene](/CAS/GIF/108-67-8.gif)
108-67-8
360 suppliers
$5.00/5 g
![1,3,5-Tris(bromomethyl)benzene](/CAS/GIF/18226-42-1.gif)
18226-42-1
178 suppliers
$30.00/1g
Yield:18226-42-1 96%
Reaction Conditions:
with N-Bromosuccinimide;dibenzoyl peroxide in tetrachloromethane at 70; for 0.6 h;Heating;
Steps:
Synthesis of 1,3,5-tris(bromomethyl)benzene (2)
Mesitylene 1 (8.6 g, 71.5 mmol), NBS (38.2 g, 214.6 mmol) and benzoyl peroxide (5.19 g, 21.4 mmol) and CCl4 (100 ml) were taken in a 150-ml RB flask. The reaction mixture was refluxed for about 6 h at 70 °C. After completion of the reaction time, the imide was removed by filtration and the solvent in the filtrate was evaporated to give the pale yellow solid of 1,3,5-tribromomesitylene. Yield: 96 %. m.p. 86-87 C; 1H NMR (300 MHz, CDCl3) d: 7.35 (s, 3H), 4.45 (s, 6H); 13C NMR(75 MHz, CDCl3)d: 139.00, 129.55, 32.19.
References:
Ponmuthu, Kottala Vijaya;Kumaraguru, Duraimurugan;Arockiam, Jesin Beneto;Velu, Sadhasivam;Sepperumal, Murugesan;Ayyanar, Siva [Research on Chemical Intermediates,2016,vol. 42,# 12,p. 8345 - 8358]
![1,3,5-BENZENETRIMETHANOL](/CAS/GIF/4464-18-0.gif)
4464-18-0
144 suppliers
$24.00/1g
![1,3,5-Tris(bromomethyl)benzene](/CAS/GIF/18226-42-1.gif)
18226-42-1
178 suppliers
$30.00/1g
![Mesitylene](/CAS/GIF/108-67-8.gif)
108-67-8
360 suppliers
$5.00/5 g
![3,5-Bis(bromomethyl)toluene](/CAS/GIF/19294-04-3.gif)
19294-04-3
130 suppliers
$16.00/1g
![1,3,5-Tris(bromomethyl)benzene](/CAS/GIF/18226-42-1.gif)
18226-42-1
178 suppliers
$30.00/1g
![3,5-Bis(bromomethyl)toluene](/CAS/GIF/19294-04-3.gif)
19294-04-3
130 suppliers
$16.00/1g
![1,3,5-Tris(bromomethyl)benzene](/CAS/GIF/18226-42-1.gif)
18226-42-1
178 suppliers
$30.00/1g
![Trimesic acid](/CAS/GIF/554-95-0.gif)
554-95-0
413 suppliers
$6.00/25g
![1,3,5-Tris(bromomethyl)benzene](/CAS/GIF/18226-42-1.gif)
18226-42-1
178 suppliers
$30.00/1g