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1,3-Benzodioxol-4-ol, 5-(methoxymethoxy)- synthesis

4synthesis methods
1,3-Benzodioxole, 5-(methoxymethoxy)-

111726-43-3
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1,3-Benzodioxol-4-ol, 5-(methoxymethoxy)-

244126-41-8
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Yield:244126-41-8 95%

Reaction Conditions:

Stage #1: 3,4-(methylenedioxy)phenyl methoxymethyl etherwith n-butyllithium;Trimethyl borate in tetrahydrofuran;
Stage #2: with dihydrogen peroxide;acetic acid at 0 - 20;

References:

Chen, Jinchun;Chen, Xiaochuan;Bois-Choussy, Michele;Zhu, Jieping [Journal of the American Chemical Society,2006,vol. 128,# 1,p. 87 - 89]