1-TERT-BUTOXY-4-NITROBENZENE synthesis
- Product Name:1-TERT-BUTOXY-4-NITROBENZENE
- CAS Number:2109-72-0
- Molecular formula:C10H13NO3
- Molecular Weight:195.22
Yield: 93%
Reaction Conditions:
in hexane;ethyl acetate
Steps:
10 4-tert-Butoxy-1-nitrobenzene (Table 1, Entries 13, 14)
Example 10 4-tert-Butoxy-1-nitrobenzene (Table 1, Entries 13, 14) 98% yield from 4-Bromo-1-nitrobenzene and 93% yield from 4-Chloro-1-nitrobenzene, eluted from silica gel using ethyl acetate/hexane (0 to 10% gradient). 1H NMR (300 MHz, CDCl3): δ 8.16 (d, 2H, J=9.0 Hz), 7.05 (d, 2H; J=9.0 Hz), 1.46 (s, 9H). 13C NMR (100 MHz, CDCl3): δ 161.87, 142.35, 125.16, 121.62, 80.56, 28.78.
References:
Yale University US6562989, 2003, B2
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$131.00/1g