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ChemicalBook CAS DataBase List N-(4-(4-methylphenyl)-3-phenyl-1,3-thiazol-2(3H)-ylidene)-N-phenylamine
1354258-84-6

N-(4-(4-methylphenyl)-3-phenyl-1,3-thiazol-2(3H)-ylidene)-N-phenylamine synthesis

3synthesis methods
-

Yield:1354258-84-6 77%

Reaction Conditions:

with triethylamine in ethanol; for 0.116667 h;Reflux;regioselective reaction;

Steps:

25 General procedure for the synthesis of N-(3,4-diphenylthiazol-2(3H)-ylidene)phenylamine (4a):

General procedure: To a mixture of aniline (1 mmol) and phenyl isothiocyanate (1 mmol) in EtOH (3 ml) under reflux, was added phenacyl bromide (1 mmol) and Et3N (0.2 mmol). After heating for the time shown in refPreviewPlaceHolderTable 1 (completion of the reaction was monitored by TLC), the mixture was cooled and the resulting solid filtered and dried to give 4a as a white powder without further purification (0.26 g, 79%).

References:

Heravi, Majid M.;Moghimi, Setareh [Tetrahedron Letters,2012,vol. 53,# 4,p. 392 - 394] Location in patent:experimental part