ChemicalBook CAS DataBase List .alpha.-D-Glucopyranoside, phenyl 1-thio-, tetraacetate

.alpha.-D-Glucopyranoside, phenyl 1-thio-, tetraacetate synthesis

6synthesis methods

Product Name:.alpha.-D-Glucopyranoside, phenyl 1-thio-, tetraacetate
CAS Number:13992-16-0
Molecular formula:C20H24O9S
Molecular Weight:440.46

1197-26-8 Synthesis

1197-26-8
16 suppliers
$400.00/25mg

2,3,4,6-Tetra-O-acetyl-alpha-D-glucopyranosyl bromide

572-09-8
332 suppliers
$10.00/1g

.alpha.-D-Glucopyranoside, phenyl 1-thio-, tetraacetate

13992-16-0
29 suppliers
$200.00/1g

Yield:13992-16-0 70%

Reaction Conditions:

with potassium phosphate;1,1,1,3,3,3-hexamethyl-2-(trimethylsilyl)-2-trisilanol;(2r,4s,5r)-2,4,5,6-Tetrakis(3,6-dichloro-9H-carbazol-9-yl)isophthalonitrile in water;1,2-dichloro-ethane at -5; for 24 h;Inert atmosphere;Irradiation;stereoselective reaction;

References:

Bi, Fangchao;Gao, Feng;Ji, Peng;Wang, Wei;Zhang, Yueteng [Chemical Science,2020,vol. 11,# 48,p. 13079 - 13084]