2-(2-Chloro-6-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane synthesis

2synthesis methods

Product Name:2-(2-Chloro-6-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane
CAS Number:1599432-38-8
Molecular formula:C12H15BClFO2
Molecular Weight:256.51

61676-62-8 Synthesis

2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

61676-62-8
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$11.19/5G

625-98-9 Synthesis

625-98-9
179 suppliers
$14.00/25g

765917-27-9 Synthesis

4-chloro-2-fluorophenylboronic aicd, pinacol ester

765917-27-9
45 suppliers
$21.00/250mg

2-(2-Chloro-6-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

1599432-38-8
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Yield:1599432-38-8 69%

Reaction Conditions:

Stage #1: 3-chlorofluorobenzenewith n-butyllithium;N,N,N,N,-tetramethylethylenediamine;diisopropylamine in tetrahydrofuran at -78; for 1.66667 h;Inert atmosphere;
Stage #2: 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane at -78 - 0;

References:

Wang, Yan;Wang, Le;Chen, Ling-Yan;Bhadury, Pinaki S.;Sun, Zhihua [Australian Journal of Chemistry,2014,vol. 67,# 4,p. 675 - 678]

625-98-9 Synthesis

625-98-9
179 suppliers
$14.00/25g

73183-34-3
564 suppliers
$6.00/5g

765917-27-9 Synthesis

765917-27-9
45 suppliers
$21.00/250mg

1599432-38-8
24 suppliers
inquiry

References

2-(2-Chloro-6-fluorophenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Related Search:

4'-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)biphenyl-4-carbonitrile 3-chloro-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzonitrile 4-Butylphenylboronic acid pinacol ester 2-BUTYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 2-(3-BENZYLOXYPHENYL)-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE