ChemicalBook CAS DataBase List (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE

(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE synthesis

7synthesis methods

Product Name:(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE
CAS Number:14212-54-5
Molecular formula:C9H10O
Molecular Weight:134.18

873-66-5
111 suppliers
$35.00/250 mg

100-52-7 Synthesis

100-52-7
942 suppliers
$17.30/2g

4518-66-5 Synthesis

4518-66-5
11 suppliers
$142.00/1g

14212-54-5
13 suppliers
$163.00/1g

Yield: 6% ， 86% ， 8%

Reaction Conditions:

with oxygen;isobutyraldehyde in acetonitrile at 45; for 8 h;enantioselective reaction;Reagent/catalyst;

Steps:

2.8. Catalytic aerobic oxidation of hydrocarbons
General procedure: The oxidation of hydrocarbons was performed in a 25-mL round-bottom flask equipped with a condenser in a thermostated oil bath at 45 °C. In a typical experiment the flask was charged with the suspension of catalyst SBA15-[Mn^III(TCPP-R*)Cl] (10.0 mg; contains 63.7 lmol Mn), 5 mL acetonitrile, 0.10 g chlorobenzene as internal standard, substrate and 5 mmol isobutyraldehyde. Dioxygen was provided using an oxygen balloon. The reaction mixture was stirred at 45 °C for 8 h. At appropriate intervals, aliquots were removed and analyzed by GC-FID. The products were identified with authentic samples and ¹H-NMR spectroscopy.

References:

Farokhi, Afsaneh;Hosseini Monfared, Hassan [Journal of Catalysis,2017,vol. 352,p. 229 - 238]

637-50-3 Synthesis