(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE
- CAS No.
- 14212-54-5
- Chemical Name:
- (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE
- Synonyms
- (2r-trans)-oxiran;1-phenylpropylene oxide;(r,r)-phenylpropyleneoxide;2-epoxypropyl)benzene(1r,2r)-(;(1,2-epoxypropyl)-,(1r,2r)-benzen;[(2R,3R)-3-Methyloxiranyl]benzene;(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE;(2R,3R)-(+)-2-METHYL-3-PHENYLOXIRANE;[2R,3R,(+)]-3-Methyl-2-phenyloxirane;(1r,2r)-(+)-1-phenyl-1,2-epoxypropane
- CBNumber:
- CB2263647
- Molecular Formula:
- C9H10O
- Molecular Weight:
- 134.18
- MDL Number:
- MFCD00064482
- MOL File:
- 14212-54-5.mol
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
---|---|
Signal word | Warning |
Hazard statements | H315-H319-H335 |
Precautionary statements | P261-P305+P351+P338 |
Hazard Codes | Xi |
Risk Statements | 36/37/38 |
Safety Statements | 26-36 |
WGK Germany | 3 |
RTECS | DA0177000 |
(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE price More Price(2)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
American Custom Chemicals Corporation | CCH0002952 | (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE 95.00% | 14212-54-5 | 1G | $751.3 | 2021-12-16 | Buy |
AHH | MT-21263 | (1R,2R)-(+)-1-Phenylpropylene oxide 97% | 14212-54-5 | 10g | $425 | 2021-12-16 | Buy |
(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Chemical Properties,Uses,Production
Synthesis
A solution of 0.05 M Na2HPO4 (10.0 mL) was added to a 25-mL solution of undiluted commercial household bleach (Clorox). The pH of the resulting buffered solution (0.55 M in NaOCl) was adjusted to pH 11.3 by addition of a few drops of 1 M NaOH solution. This solution was cooled to 0 °C and then added at once to a 0 °C solution of the manganese catalyst (260 mg, 0.4 mmol) and cis-o-methylstyrene (1.18 g, 10 mmol) in 10 mL of CH2Cl2. The two-phase mixture was stirred at room temperature, and the reaction progress was monitored by TLC. After 3 h, 100 mL of hexane was added to the mixture and the brown organic phase was separated, washed twice with 100 mL of H2O and once with 100 mL of saturated NaCl solution, and then dried (Na2SO4). After solvent removal, the residue was purifified by flflash chromatography on silica gel to afford the epoxide (0.912 g, 68%). The ee of the epoxide was determined to be 84% by 1 H NMR analysis in the presence of Eu(hfc)3.
Reference: Zhang, W.; Jacobsen, E. N. J. Org. Chem. 1991, 56, 2296−2298.
Uses
Chiral building block. Tool for studying enzyme hydrolysis rates.
(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Preparation Products And Raw materials
Raw materials
Preparation Products
(1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE Suppliers
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44700 | 61 |
Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51471 | 80 |
Shandong Ono Chemical Co., Ltd. | 0539-6362799 20) | China | 9998 | 58 | |
Aikon International Limited | 025-66113011 18112977050 | sales01@aikonchem.com | China | 16028 | 58 |
Nanjing Shizhou Biology Technology Co.,Ltd | 13675144456 | sean.lv@synzest.com | China | 10787 | 58 |
QUALITY CONTROL SOLUTIONS LTD. | 0755-66853366; 13670046396 | ORDERS@QCSRM.COM | China | 18899 | 58 |
Supplier | Advantage |
---|---|
Energy Chemical | 61 |
Sigma-Aldrich | 80 |
Shandong Ono Chemical Co., Ltd. | 58 |
Aikon International Limited | 58 |
Nanjing Shizhou Biology Technology Co.,Ltd | 58 |
QUALITY CONTROL SOLUTIONS LTD. | 58 |
View Lastest Price from (1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2021-07-02 | (1R,2R)-(+)-1-Phenylpropylene oxide
14212-54-5
|
US $15.00-10.00 / KG | 1KG | 99%+ HPLC | Monthly supply of 1 ton | Zhuozhou Wenxi import and Export Co., Ltd |
- (1R,2R)-(+)-1-Phenylpropylene oxide
14212-54-5
- US $15.00-10.00 / KG
- 99%+ HPLC
- Zhuozhou Wenxi import and Export Co., Ltd
14212-54-5((1R,2R)-(+)-1-PHENYLPROPYLENE OXIDE)Related Search:
1of4