2-METHYLDECANE synthesis
- Product Name:2-METHYLDECANE
- CAS Number:6975-98-0
- Molecular formula:C11H24
- Molecular Weight:156.31
4196-96-7
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6975-98-0
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$99.00/100mg
Yield:6975-98-0 94%
Reaction Conditions:
with palladium on activated carbon;hydrogen;acetic acid;europium(III) trifluoromethanesulfonate in ethyl acetate at 200; under 30003 Torr; for 16 h;Catalytic behavior;Autoclave;Green chemistry;Reagent/catalyst;Solvent;
Steps:
2.2. General Procedure for HDO of 1 and 2 to 3 and 4
General procedure: Desired amount of substrate (1 or 2) was weighed and placedinto the glass insert with magnetic stirring bar. After this, appro-priate amount of solvent, cocatalyst (HOTf (≥99%), Eu(OTf)3(98%),YbCl3(99.9%), Nd(OTf)3(98%), FeCl3(97%) Sigma Aldrich; Hf(OTf)4(98%), Fe(OTf)3(90% tech.), EuCl3(99.9%), Sc(OTf)3(98%), Y(OTf)3,LaCl3(99.9%) and La(OTf)3(99%) Alfa Aesar; InCl3(98%) Fluka; andAlCl3(98.7%) Baker) and 0.4 mol-% of Pd/C (5 w-%, Sigma Aldrich)were added. The glass insert was placed into the autoclave, whichwas then closed and placed into a heating mantle (Roth 30 S). Theautoclave was pressurized with H2to 40 bars (at room tempera-ture) and heated at 200C for desired time (See SI for more details).After heating, the reaction solution was cooled to room tempera-ture, filtered and diluted with EtOAc or hexane (depending on thesolvent used) to 50 ml. From this solution, an aliquot of 1.25 ml wastaken, 0.1 ml of internal standard (acetophenone) was added andthe resulting solution was diluted with EtOAc or hexane (10 ml).The yields of 3 and 4 were determined from this solution withGC-FID.
References:
Keskiv?li, Juha;Wrigstedt, Pauli;Lagerblom, Kalle;Repo, Timo [Applied Catalysis A: General,2017,vol. 534,p. 40 - 45]
4325-51-3
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6975-98-0
49 suppliers
$99.00/100mg
111-66-0
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$10.00/10ml
108-23-6
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$80.00/10g
6975-98-0
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$99.00/100mg
629-27-6
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$5.00/5g
6975-98-0
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$99.00/100mg
544-76-3
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$6.00/25g
807329-97-1
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$109.00/4x25ml
629-27-6
149 suppliers
$5.00/5g
6975-98-0
49 suppliers
$99.00/100mg