2-Pentenoic acid, 2,4,4-trimethyl-, (2E)- synthesis
3synthesis methods
- Product Name:2-Pentenoic acid, 2,4,4-trimethyl-, (2E)-
- CAS Number:60065-21-6
- Molecular formula:C8H14O2
- Molecular Weight:142.2
Yield:60065-21-6 21%
Reaction Conditions:
with manganese;(1,2-dimethoxyethane)dichloronickel(II);Bathocuproine;tert-butyl alcohol in N,N-dimethyl-formamide at 60; for 36 h;Schlenk technique;regioselective reaction;
References:
Wang, Xueqiang;Nakajima, Masaki;Martin, Ruben [Journal of the American Chemical Society,2015,vol. 137,# 28,p. 8924 - 8927] Location in patent:supporting information