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ChemicalBook CAS DataBase List 3-Bromo-6-methoxypyridazine
17321-29-8

3-Bromo-6-methoxypyridazine synthesis

2synthesis methods
-

Yield: 92%

Reaction Conditions:

with potassium carbonate at 90; for 15 h;Sealed tube;

Steps:

8.1 Example 8: Synthesis of 1-(5-((1-(6-methoxypyridazin-3-yl)-2-oxo-1,2-dihydropyridin-3-yl)amino)-7-(methylamino)pyrazolo[1,5-a]pyrimidin-3-yl)-3-methylurea (17)
Step 1:
To a suspension of 3,6-dibromopyridazine (1.0 g, 1.0 eq) in MeOH (50 mL) was added K2C03 (1.2 g, 2.0 eq).
The resulting mixture was heated at 90° C. in a sealed-tube for 15 hrs.
The solvent was removed in vacuo.
The residue was dissolved in ethyl acetate, washed with water and brine to afford 3-bromo-6-methoxypyridazine (14) (725 mg, 92%) which was used without further purification.

References:

Ventyx Biosciences, Inc. US2021/139486, 2021, A1 Location in patent:Paragraph 0350; 0351

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