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3-CHLORO-4-METHYLBENZENESULFONIC ACID synthesis

5synthesis methods
The production of 3-Chloro-4-methylbenzenesulfonic Acid is from toluene by sulfonation with anhydrous sulfuric acid, followed by chlorination with gaseous chlorine.
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Yield:98-34-0 82%

Reaction Conditions:

with hydrogenchloride;dihydrogen peroxide in water at 45; for 4 h;Temperature;

References:

Mukhopadhyay, Sudip;Chandnani, Kavita H.;Chandalia, Sampatraj B. [Organic Process Research and Development,1999,vol. 3,# 3,p. 196 - 200]