ChemicalBook CAS DataBase List 3-METHYL-2-OXAZOLIDONE

3-METHYL-2-OXAZOLIDONE synthesis

10synthesis methods

Product Name:3-METHYL-2-OXAZOLIDONE
CAS Number:19836-78-3
Molecular formula:C4H7NO2
Molecular Weight:101.1

124-38-9
129 suppliers
$175.00/23402

107-06-2 Synthesis

107-06-2
425 suppliers
$14.00/25g

74-89-5 Synthesis

74-89-5
7 suppliers
$13.44/25ML

19836-78-3
108 suppliers
$12.00/5g

Yield: 94%

Reaction Conditions:

in water at 120; under 3750.38 Torr; for 2 h;

Steps:

1
1 g of 1,2-dichloroethane and 5.5 g of an aqueous 40% methylamine solution were charged in a 20 ml pressure vessel made of SUS316 and 1.9 g of a carbon dioxide gas was absorbed under a pressure of 0.5 MPa, followed by heating at 120° C. for 2 hours. After cooling the pressure vessel, the contents were removed and analyzed by gas chromatography. As a result, N-methyl-2-oxazolidinone was obtained in a 94% yield based on 1,2-dichloroethane. Hydrogen chloride produced, as a by-product, during the reaction was neutralized with excess amine.

References:

Mitsubishi Gas Chemical Company, Inc. US2005/154200, 2005, A1 Location in patent:Page/Page column 4