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3-methyl-2-(trifluoromethyl)aniline synthesis

1synthesis methods
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Yield:106877-29-6 12% ,106877-30-9 18% ,106877-31-0 18%

Reaction Conditions:

with α-picoline;sodium metabisulfite;sulfur dioxide;zinc in N,N-dimethyl-formamide at 20; under 2250.2 - 3750.3 Torr; for 2 h;

References:

Tordeux, Marc;Langlois, Bernard;Wakselman, Claude [Journal of the Chemical Society. Perkin transactions I,1990,# 8,p. 2293 - 2299]