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ChemicalBook CAS DataBase List 4-TERT-BUTYL-PHENYL-HYDRAZINE
61765-93-3

4-TERT-BUTYL-PHENYL-HYDRAZINE synthesis

4synthesis methods
3972-65-4 Synthesis
1-Bromo-4-tert-butylbenzene

3972-65-4
323 suppliers
$8.00/10g

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Yield:-

Reaction Conditions:

Stage #1:1-bromo-4-tert-butylbenzene with t-butoxycarbonylhydrazine;t-BuBrettPhos;[tBuBrettPhosPd(allyl)]OTf;sodium t-butanolate in water at 45; for 1.5 h;Inert atmosphere;
Stage #2: with sulfuric acid in ethanol;water at 90 - 95;Inert atmosphere;Sealed tube;

References:

Akporji, Nnamdi;Braga, Felipe C.;Gabriel, Christopher M.;Landstrom, Evan B.;Lee, Nicholas R.;Lipshutz, Bruce H. [Organic Letters,2020] Location in patent:supporting information

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