Phosphine, dicyclohexyl[2-(9-phenanthrenyl)phenyl]- synthesis
- Product Name:Phosphine, dicyclohexyl[2-(9-phenanthrenyl)phenyl]-
- CAS Number:405919-41-7
- Molecular formula:C32H35P
- Molecular Weight:450.59
694-80-4
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Yield:405919-41-7 37%
Reaction Conditions:
Stage #1: 9-bromophenanthrenewith magnesium in tetrahydrofuran at 60;
Stage #2: 2-bromo-1-chlorobenzene in tetrahydrofuran at 60; for 2.33333 h;
Stage #3: chlorodicyclohexylphosphanewith copper(l) chloride in tetrahydrofuran at 20; for 48 h;Further stages.;
References:
Yin, Jingjun;Rainka, Matthew P.;Zhang, Xiao-Xiang;Buchwald, Stephen L. [Journal of the American Chemical Society,2002,vol. 124,# 7,p. 1162 - 1163]