Benzenamine, N-(1-methylethylidene)- synthesis

11synthesis methods

Product Name:Benzenamine, N-(1-methylethylidene)-
CAS Number:1124-52-3
Molecular formula:C9H11N
Molecular Weight:133.19

62-53-3 Synthesis

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1124-52-3
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Yield:1124-52-3 97%

Reaction Conditions:

with microporous zeolite at 230; for 24 h;Sealed tube;Autoclave;

Steps:

Synthesis of 2,2,4-trimethyl-1,2-dihydroquinoline (1) and N-phenyl-2-propanimine (2).

General procedure: Aniline (0.1 g, 1 mmol), acetone (0.3 g, 5 mmol), and a catalyst (0.04 g, 10% calculated on the aniline-acetone mixture) were placed into a tube. The sealed tube was transferred into an autoclave, which was heated to 230 °C in a thermostatically controlled oven during 24 h with continuous rotation. After the reaction reached completion, the autoclave was cooled to ~20 °C, the tube was unsealed. The reaction mixture was filtered from the catalyst

References:

Grigor’eva;Filippova;Gataulin;Bubennov;Agliullin;Kutepov;Narender, Nama [Russian Chemical Bulletin,2017,vol. 66,# 11,p. 2115 - 2121][Izv. Akad. Nauk, Ser. Khim.,2017,# 11,p. 2115 - 2121,7]