ChemicalBook CAS DataBase List Cyclohexyldimethoxymethylsilane

Cyclohexyldimethoxymethylsilane synthesis

4synthesis methods

Product Name:Cyclohexyldimethoxymethylsilane
CAS Number:17865-32-6
Molecular formula:C9H20O2Si
Molecular Weight:188.34

16881-77-9
124 suppliers
$53.39/5g

110-83-8
290 suppliers
$11.00/25g

17865-32-6
180 suppliers
$6.00/25g

Yield:17865-32-6 65%

Reaction Conditions:

with C₂₂H₃₁N₂O₇Rh in neat (no solvent) at 25; for 12 h;Reagent/catalyst;Temperature;

Steps:

11 Examples 11 and 12
To a cyclohexene solution (0.5 mL) of Rh (Phebox-iPr) (OAc) 2 OH 2 (5.4 mg, 0.010 mmol) represented by the following formula,Hydrosilane (amount shown in Table 5) listed in Table 5 was added.After stirring at 25 ° C. for 12 hours,Pentadecane (42.5 mg, 55.2 μL, 0.20 mmol) was added and the yield of each product was determined by measuring GC. As a result, the product of Example 11 (n = 1) was obtained in a yield of 65% and the product of Example 12 (n = 0) in a yield of 72%.

References:

NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY;Hayashi, Kazufumi;Matsumoto, Kazuhiro;Nakajima, Yumiko;Shimada, Shigeru;Sato, Kazuhiko JP2018/118920, 2018, A Location in patent:Paragraph 0022; 0025; 0028; 0031; 0034; 0035; 0036

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1634-04-4 Synthesis