D-Glucuronic acid synthesis

Yield:6556-12-3 75 %Chromat.

Reaction Conditions:

with oxygen in water at 70; under 11251.1 Torr; for 4 h;Catalytic behavior;Autoclave;High pressure;Temperature;Reagent/catalyst;

Steps:

Oxidation reactions

General procedure: The reactions were carried out in 75mL stainless steel reactors (Series 5000 Multiple Reactor System, Parr Instrument Co., USA). The test reactor unit is a magnetically stirred high-pressure reactor equipped with a Parr 4843 controller for the setup and control of reaction temperature and stirring speed. Reactor pressure measurements were accomplished via a pressure transducer attached to the reactor. Temperature, pressure and stirring speed are recorded by a Space View data acquisition system. The total volume of carbohydrate aqueous solution used was 10mL and the charged weight of catalyst was about 20mg. The catalytic reactions were carried out for the desired time or temperature without any base addition. The oxygen pressure was of 15bar in all experiments

References:

Wojcieszak, Robert;Cuccovia, Iolanda M.;Silva, Márcia A.;Rossi, Liane M. [Journal of Molecular Catalysis A: Chemical,2016,vol. 422,p. 35 - 42]