![](/CAS/GIF/2168-93-6.gif)
DI-N-BUTYL SULFOXIDE synthesis
- Product Name:DI-N-BUTYL SULFOXIDE
- CAS Number:2168-93-6
- Molecular formula:C8H18OS
- Molecular Weight:162.29
![Dibutyl sulfide](/CAS/GIF/544-40-1.gif)
544-40-1
298 suppliers
$10.00/5mL
![DI-N-BUTYL SULFONE](/CAS/GIF/598-04-9.gif)
598-04-9
51 suppliers
$60.00/500mg
![Butyl disulfide](/CAS/GIF/629-45-8.gif)
629-45-8
153 suppliers
$24.51/10 mL
![DI-N-BUTYL SULFOXIDE](/CAS/GIF/2168-93-6.gif)
2168-93-6
61 suppliers
$21.10/5g
![Butyraldehyde](/CAS/GIF/123-72-8.gif)
123-72-8
402 suppliers
$12.32/25ML
Yield:-
Reaction Conditions:
with oxygen;[5,6]fullerene-C70 in tolueneQuantum yield;Kinetics;Irradiation;
Steps:
General procedure: The kinetics of the photosensitized oxidation reaction of dibutyl sulfide with air oxygen was investigatedin a toluene solution in 20mL scintillation vials usedas a static reactor. The choice of toluene as the solventis due to high solubility of fullerenes in it, which is1.4 g/L [33]. The experimental setup is schematized inFig. 1. The reaction mixture was prepared by adding17.5 μL of dibutyl sulfide and an accurately measuredaliquot of naphthalene (~12 mg) to 10 mL of 0.21 μMC70 fullerene solution in toluene. Naphthalene wasused as an internal standard for quantitative chromatographic determination of the reactants and products.A vial was secured with clamps above a LED lamp(Fig. 1). A narrow fluoroplastic tube was introduced toa reaction mixture through an opening in a fluoroplastic stopper, through which air was supplied with a flowrate of 100 mL/min. Aircooling of the reactor with afan allowed maintaining the reactor temperature closeto room temperature. A 10W light emitting diodelamp SDO210 (ASD Corporation, Hong Kong)with a ZhS17 light filter transmitting light in therange of 480-800 nm was used as a light source. Thelight intensity was measured using a 20mL Pyrex vial of 25 mm in diameter, filled with the reaction mixture,mounted at different distances from the light source.
References:
Arsentyev;Vorontsov;Parmon [High Energy Chemistry,2015,vol. 49,# 3,p. 167 - 172][Khim. Vys. Energ.,2015,vol. 49,# 3,p. 194 - 199,6]
![Dibutyl sulfide](/CAS/GIF/544-40-1.gif)
544-40-1
298 suppliers
$10.00/5mL
![DI-N-BUTYL SULFOXIDE](/CAS/GIF/2168-93-6.gif)
2168-93-6
61 suppliers
$21.10/5g
![Dibutyl sulfide](/CAS/GIF/544-40-1.gif)
544-40-1
298 suppliers
$10.00/5mL
![DI-N-BUTYL SULFONE](/CAS/GIF/598-04-9.gif)
598-04-9
51 suppliers
$60.00/500mg
![DI-N-BUTYL SULFOXIDE](/CAS/GIF/2168-93-6.gif)
2168-93-6
61 suppliers
$21.10/5g
![tert-Butyl hydroperoxide](/CAS/GIF/75-91-2.gif)
75-91-2
155 suppliers
$26.00/100g
![Dibutyl sulfide](/CAS/GIF/544-40-1.gif)
544-40-1
298 suppliers
$10.00/5mL
![DI-N-BUTYL SULFOXIDE](/CAS/GIF/2168-93-6.gif)
2168-93-6
61 suppliers
$21.10/5g
![tert-Butanol](/CAS/GIF/75-65-0.gif)
75-65-0
741 suppliers
$10.00/10ml