![](/CAS/GIF/80-10-4.gif)
Dichlorodiphenylsilane synthesis
- Product Name:Dichlorodiphenylsilane
- CAS Number:80-10-4
- Molecular formula:C12H10Cl2Si
- Molecular Weight:253.2
![Diphenylsilane](/CAS/GIF/775-12-2.gif)
775-12-2
202 suppliers
$10.00/1g
![Dichlorodiphenylsilane](/CAS/GIF/80-10-4.gif)
80-10-4
208 suppliers
$10.00/5g
Yield:80-10-4 94.1%
Reaction Conditions:
with copper(l) iodide;copper dichloride in diethyl ether at 20; for 4 h;Inert atmosphere;
Steps:
Synthesis of diphenyldichlorosilane
A mixture of 18.44g (0.1mol) of Ph2SiH2, 53.8g (0.4mol) of anhydrous CuCl2, 1.44g (0.0076mol) of anhydrous CuI, 120g of ceramic spheres and 60mL of diethyl ether was stirred with a mechanical stirrer at 400rpm at room temperature for 4h. The mixture was filtered, and the filtrate was concentrated. The residue was distilled under reduced pressure to give Ph2SiCl2 (23.8g, 94.1%) as a colorless liquid. Bp. 150°C (210pa): 1H NMR: δ 7.49-7.83 [m, 10H, Si(C6H5)]. 13C NMR: δ 128.47, 131.87, 131.91, 134.11 [m, 12C, Si(C6H5)]. 29Si NMR: δ 5.41 [s, 1Si, Ph2SiCl2].
References:
Wang, Wenchao;Tan, Yongxia;Xie, Zemin;Zhang, Zhijie [Journal of Organometallic Chemistry,2014,vol. 769,p. 29 - 33]
![(4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLAN-2-YL)BENZENE](/CAS/GIF/24388-23-6.gif)
24388-23-6
206 suppliers
$6.00/5g
![Phenyltrichlorosilane](/CAS/GIF/98-13-5.gif)
98-13-5
219 suppliers
$14.00/25g
![Triphenylsilyl chloride](/CAS/GIF/76-86-8.gif)
76-86-8
202 suppliers
$16.00/5g
![Dichlorodiphenylsilane](/CAS/GIF/80-10-4.gif)
80-10-4
208 suppliers
$10.00/5g
![Bromobenzene](/CAS/GIF/108-86-1.gif)
108-86-1
496 suppliers
$10.00/5g
![Dichlorodiphenylsilane](/CAS/GIF/80-10-4.gif)
80-10-4
208 suppliers
$10.00/5g
![Phenyltrichlorosilane](/CAS/GIF/98-13-5.gif)
98-13-5
219 suppliers
$14.00/25g
![Chlorobenzene](/CAS/GIF/108-90-7.gif)
108-90-7
643 suppliers
$10.00/25G
![CHLOROPHENYLSILANE 97](/CAS/GIF/4206-75-1.gif)
4206-75-1
34 suppliers
$150.00/1 g
![Dichlorodiphenylsilane](/CAS/GIF/80-10-4.gif)
80-10-4
208 suppliers
$10.00/5g