ChemicalBook CAS DataBase List Ethyl methyl carbonate

Ethyl methyl carbonate synthesis

11synthesis methods

Product Name:Ethyl methyl carbonate
CAS Number:623-53-0
Molecular formula:C4H8O3
Molecular Weight:104.1

616-38-6 Synthesis

616-38-6
660 suppliers
$5.00/5 g

105-58-8
450 suppliers
$14.00/25g

623-53-0
281 suppliers
$44.79/10ml

Yield:623-53-0 83.39%

Reaction Conditions:

with Zeolitic imidazole framework (ZIF)-67 at 100; for 24 h;Reagent/catalyst;Concentration;

Steps:

2.3.1 Typical procedure for the synthesis of EMC
A mixture of DMC (9.000g, 0.1mol), DEC (11.800g, 0.1mol) and catalyst (0.200g, 2wt.%), was charged into a 50mL flask equipped with a magnetic stirring and a reflux condenser. The reaction mixture was then heated to 100°C with continuous stirring. After 24h, the mixture was cooled to room temperature. And the product was filtered and analyzed by a gas chromatograph (GC, Agilent-7890A) equipped with a flame-ionized detector. In the reusability experiment, catalysts were separated by filtration and washed using methanol (10mL×3), then dried in air at 150°C for the next reaction.

References:

Yang, Lili;Yu, Lin;Sun, Ming;Gao, Cheng [Catalysis Communications,2014,vol. 54,p. 86 - 90]

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64-17-5 Synthesis