![](/CAS/GIF/1066-40-6.gif)
hydroxytrimethylsilane synthesis
- Product Name:hydroxytrimethylsilane
- CAS Number:1066-40-6
- Molecular formula:C3H10OSi
- Molecular Weight:90.2
![BENZYLOXYTRIMETHYLSILANE](/CAS/GIF/14642-79-6.gif)
14642-79-6
77 suppliers
$38.00/5g
![hydroxytrimethylsilane](/CAS/GIF/1066-40-6.gif)
1066-40-6
215 suppliers
$14.00/1g
Yield:1066-40-6 97%
Reaction Conditions:
with palladium-platinum;hydrogen;aniline in N,N-dimethyl acetamide at 20; for 2 h;
Steps:
37 Example 37
A total of 9.1 mg of ASCA-2 (Pd 4.5 mass %, Pt 0.5 mass %) produced by N.E. Chemcat Corporation (2.5 mol % when calculated based on benzyloxy groups) and trimethylbenzyloxysilane (27.0 mg, 0.150 mmol) obtained in Synthesis Example 5 were placed into a two-neck flask equipped with a magnetic stirrer, and 1.6 ml of N,N-dimethylacetamide (DMAc) and aniline (NH2Ph, 0.9 mg) in a 0.064-fold substance amount, when calculated based on benzyloxy groups, were added thereto. After replacing with hydrogen gas, a reaction was conducted for 2.0 h at room temperature. The catalyst was then filtered out with a filter. The 1H, 13C-NMR (DMAc/THF-d8: 2.1 ppm), and 29Si-NMR (DMAc/THF-d8: 10.1 ppm) analysis confirmed that trimethylsilanol, etc. was produced. The results relating to the yield of the product, etc. are presented in Table 12.
References:
NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY;Igarashi, Masayasu;Shimada, Shigeru;Sato, Kazuhiko;Matsumoto, Tomohiro US2017/183363, 2017, A1 Location in patent:Paragraph 0216; 0217
![Trimethylfluorosilane](/CAS/GIF/420-56-4.gif)
420-56-4
71 suppliers
$95.00/10 g
![hydroxytrimethylsilane](/CAS/GIF/1066-40-6.gif)
1066-40-6
215 suppliers
$14.00/1g
![Hexamethyldisilazane](/CAS/GIF/999-97-3.gif)
999-97-3
635 suppliers
$9.00/5 g
![hydroxytrimethylsilane](/CAS/GIF/1066-40-6.gif)
1066-40-6
215 suppliers
$14.00/1g
201230-82-2
1 suppliers
inquiry
![1-PHENYL-2-(TRIMETHYLSILYL)ACETYLENE](/CAS/GIF/2170-06-1.gif)
2170-06-1
104 suppliers
$11.00/1g
![hydroxytrimethylsilane](/CAS/GIF/1066-40-6.gif)
1066-40-6
215 suppliers
$14.00/1g
![1-Indanone](/CAS/GIF/83-33-0.gif)
83-33-0
549 suppliers
$6.00/5g