ChemicalBook CAS DataBase List METHYL 3-BUTENOATE

METHYL 3-BUTENOATE synthesis

8synthesis methods

Product Name:METHYL 3-BUTENOATE
CAS Number:3724-55-8
Molecular formula:C5H8O2
Molecular Weight:100.12

35466-83-2 Synthesis

35466-83-2
128 suppliers
$16.00/5g

3724-55-8
87 suppliers
$106.00/1g

Yield:3724-55-8 100%

Reaction Conditions:

with carbon monoxide;triphenylphosphine;palladium diacetate

Steps:

1 EXAMPLE 1
EXAMPLE 1 Allyl methyl carbonate (11.6 g, 0.1 mole), palladium acetate (22.4 mg, 0.1 mmole) and triphenylphosphine (78.9 mg, 0.3 mmole) were placed in a 100-mlpressure vessel equipped with magnetic stirrer. The vessel was closed and flushed with purified N₂ and then charged with carbon monoxide to a pressure of 1000 psig. The vessel was heated to 100° C. while the contents were stirred. After 2 hours, the vessel was cooled to room temperature and the contents analyzed by gas chromatography. p-Diisopropylbenzene was used as standard for quantification of the product. The result showed 10.0 g of methyl 3-butenoate had been formed. The yield was accordingly 100 percent.

References:

The Dow Chemical Company US4450285, 1984, A

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106-95-6 Synthesis