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5448-35-1

N,N-Di-n-propyl-3-MethylbenzaMide, 97% synthesis

1synthesis methods
-

Yield:5448-35-1 86%

Reaction Conditions:

Stage #1: di-n-propylaminewith ethylmagnesium bromide in tetrahydrofuran;diethyl ether at 30; for 1 h;
Stage #2: 3-Methylbenzonitrilewith ethylmagnesium bromide in tetrahydrofuran;diethyl ether at 30; for 1 h;
Stage #3: with hydrogenchloride in tetrahydrofuran;diethyl ether;dichloromethane at 22;

References:

Bhattacharya, Apurba;Plata, Robert Erik;Villarreal, Victor;Muramulla, Savitha;Wu, Jiejun [Tetrahedron Letters,2006,vol. 47,# 4,p. 505 - 506]