![](/CAS/20200611/GIF/38614-06-1.gif)
Phenol, 2-tricyclo[3.3.1.13,7]dec-1-yl- synthesis
- Product Name:Phenol, 2-tricyclo[3.3.1.13,7]dec-1-yl-
- CAS Number:38614-06-1
- Molecular formula:C16H20O
- Molecular Weight:228.33
![1-Bromoadamantane](/CAS/GIF/768-90-1.gif)
768-90-1
396 suppliers
$10.00/5g
![Phenol](/CAS/20180808/GIF/108-95-2.gif)
108-95-2
725 suppliers
$14.00/25g
![Phenol, 2-tricyclo[3.3.1.13,7]dec-1-yl-](/CAS/20200611/GIF/38614-06-1.gif)
38614-06-1
9 suppliers
inquiry
![4-(1-ADAMANTYL)PHENOL](/CAS/GIF/29799-07-3.gif)
29799-07-3
133 suppliers
$9.00/250mg
Yield:29799-07-3 83% ,38614-06-1 17%
Reaction Conditions:
with molybdenum hexacarbonyl at 120; for 2 h;Sealed tube;regioselective reaction;
Steps:
Alkylation of aromatic compound with 1-bromoadamantane. General procedure.
General procedure: Into a pressure microreactor of stainless steel of capacity 17 mL or into a glass ampule of capacity 10 mL (the results of parallel runs differed insignificantly) was charged 1-3 mmol of catalyst [Mo(CO)6, MoO2(acac)2, Cr(CO)6,CoBr2, CuBr, CuBr2, W(CO)6], 100 mmol of 1-bromoadamantane, and 500 mmol of aromatic compound, the reactor was hermetically closed (the ampule was sealed) and heated at 110-130° for 1-3 h. On completing the reaction the reactor (ampule) was cooled to room temperature, opened, the reaction mixture was neutralized with NaHCO3 and filtered through a bed of Al2O3. The unreacted aromatic compound was distilled off, the residue was distilled in propanol).
References:
Khusnutdinov;Shchadneva;Khisamova [Russian Journal of Organic Chemistry,2015,vol. 51,# 11,p. 1545 - 1550][Zh. Org. Khim.,2015,vol. 51,# 11,p. 1576 - 1581,6]
![2-(Adamantan-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane](/CAS/20210111/GIF/1357000-33-9.gif)
1357000-33-9
6 suppliers
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![Phenol, 2-tricyclo[3.3.1.13,7]dec-1-yl-](/CAS/20200611/GIF/38614-06-1.gif)
38614-06-1
9 suppliers
inquiry
![1-Adamantanol](/CAS/GIF/768-95-6.gif)
768-95-6
418 suppliers
$10.00/5g
![Phenol](/CAS/20180808/GIF/108-95-2.gif)
108-95-2
725 suppliers
$14.00/25g
![Phenol, 2-tricyclo[3.3.1.13,7]dec-1-yl-](/CAS/20200611/GIF/38614-06-1.gif)
38614-06-1
9 suppliers
inquiry
![4-(1-ADAMANTYL)PHENOL](/CAS/GIF/29799-07-3.gif)
29799-07-3
133 suppliers
$9.00/250mg
![1-Chloroadamantane](/CAS/GIF/935-56-8.gif)
935-56-8
187 suppliers
$37.00/5g
![Phenol](/CAS/20180808/GIF/108-95-2.gif)
108-95-2
725 suppliers
$14.00/25g
![Phenol, 2-tricyclo[3.3.1.13,7]dec-1-yl-](/CAS/20200611/GIF/38614-06-1.gif)
38614-06-1
9 suppliers
inquiry
![4-(1-ADAMANTYL)PHENOL](/CAS/GIF/29799-07-3.gif)
29799-07-3
133 suppliers
$9.00/250mg