ChemicalBook CAS DataBase List (S)-(+)-2-TERT-BUTYLAMINO-1-PHENYLETHAN&

(S)-(+)-2-TERT-BUTYLAMINO-1-PHENYLETHAN& synthesis

5synthesis methods

Product Name:(S)-(+)-2-TERT-BUTYLAMINO-1-PHENYLETHAN&
CAS Number:14467-32-4
Molecular formula:C12H19NO
Molecular Weight:193.29

Ethanone, 2-[(1,1-dimethylethyl)imino]-1-phenyl-

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(S)-(+)-2-TERT-BUTYLAMINO-1-PHENYLETHAN&

14467-32-4
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Yield:14467-32-4 91%

Reaction Conditions:

with formic acid;RhCl[(R,R)-TsDPEN](C₅Me₅);triethylamine in N,N-dimethyl-formamide at 20; for 24 h;Inert atmosphere;optical yield given as %ee;enantioselective reaction;

References:

Tafelska-Kaczmarek, Agnieszka;Prewysz-Kwinto, Andrzej;Skowerski, Krzysztof;Pietrasiak, Katarzyna;Kozakiewicz, Anna;Zaidlewicz, Marek [Tetrahedron Asymmetry,2010,vol. 21,# 18,p. 2244 - 2248] Location in patent:experimental part

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14467-51-7 Synthesis