(S,S)-1-N-Boc-AMino-2-aMinoindane synthesis

3synthesis methods

Product Name:(S,S)-1-N-Boc-AMino-2-aMinoindane
CAS Number:597555-55-0
Molecular formula:C14H20N2O2
Molecular Weight:248.32

218151-53-2
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597555-55-0
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Yield:597555-55-0 63%

Reaction Conditions:

Stage #1: tert-butyl [(1S,2R)-2-hydroxy-2,3-dihydro-1H-inden-1-yl]-carbamatewith di-isopropyl azodicarboxylate;triphenylphosphine in tetrahydrofuran; for 0.166667 h;Inert atmosphere;
Stage #2: with diphenyl phosphoryl azide in tetrahydrofuran at 20;
Stage #3: with triphenylphosphine in tetrahydrofuran at 20 - 50; for 8 h;

References:

Gao, Yaojun;Ren, Qiao;Wu, Hao;Li, Maoguo;Wang, Jian [Chemical Communications,2010,vol. 46,# 48,p. 9232 - 9234] Location in patent:supporting information; experimental part

904295-56-3 Synthesis

Carbamic acid, N-[(1S,2R)-2,3-dihydro-2-[(methylsulfonyl)oxy]-1H-inden-1-yl]-, 1,1-dimethylethyl ester

904295-56-3
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597555-55-0
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References

24424-99-5 Synthesis

24424-99-5
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597555-55-0
14 suppliers
$150.00/0.1/ G

References