Trioctylmethylammonium iodide synthesis
- Product Name:Trioctylmethylammonium iodide
- CAS Number:35675-86-6
- Molecular formula:C25H54IN
- Molecular Weight:495.61
Yield:35675-86-6 100%
Reaction Conditions:
in tetrahydrofuran at 40; for 12 h;Inert atmosphere;
Steps:
3.2. Synthesis of Methyltrioctylammonium Iodide ([MTOA][I])
Following a standard preparation [21], iodomethane (4.44 g, 31 mmol) was added dropwise toa stirred solution of trioctylamine (8.85 g, 25 mmol) in THF (100 mL), and the mixture was stirredat 40 °C for 12 h under a flow of N2. The crude mixture was concentrated under vacuum to yield aviscous orange oil (100%) and diluted with toluene to form a 1.0 M stock solution.1H NMR (500 MHz, CDCl3): δH 3.41-3.35 (m, 6H, NCH2), 3.24 (s, 3H, NCH3), 1.74-1.64 (m, 6H,CH2), 1.43-1.23 (m, 30H, CH2), 0.89 (t, J = 6.8 Hz, 9H, CH2CH3). 13C{1H} NMR (126 MHz, CDCl3): δC61.70, 48.83, 31.62, 29.10, 29.01, 26.30, 22.57, 22.43, 14.04.
References:
Kinsman, Luke M. M.;Love, Jason B.;Morrison, Carole A.;Ngwenya, Bryne T. [Molecules,2020,vol. 25,# 18]
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