Tris(2-(2-methoxyethoxy)ethyl)amine synthesis
- Product Name:Tris(2-(2-methoxyethoxy)ethyl)amine
- CAS Number:70384-51-9
- Molecular formula:C15H33NO6
- Molecular Weight:323.43
627-42-9
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$6.00/5g
283-56-7
223 suppliers
$28.00/25g
70384-51-9
227 suppliers
$15.00/1g
Yield:70384-51-9 86.3%
Reaction Conditions:
with tetrabutylammomium bromide;potassium hydroxide in dimethyl sulfoxide at 60 - 120;Catalytic behavior;Inert atmosphere;Autoclave;Large scale;Reagent/catalyst;Solvent;
Steps:
2.1; 3.2 The second step: synthesis of tris(3,6-dioxaheptyl)amine
Under a nitrogen atmosphere, a 2-chloroethyl methyl ether 14.92 Kg (157.8 mol, 4 eq) was charged into a 50 L stainless steel reactor.Triethanolamine borate 6.2Kg (39.46mol, 1eq), tetrabutylammonium bromide 1.2Kg and dimethyl sulfoxide 28Kg, heated to 60At °C, 7.75Kg (138mol, 3.5eq) of potassium hydroxide was added in batches, and the reaction was carried out by heating to 120 ° C for 5-6 hours.By GC, a yellow oily liquid tris(3,6-dioxaheptyl)amine 11.01 Kg was obtained by distillation, HNMR purity: 99.4%, yield: 86.3%.
References:
Pulasi Science And Technology (Shanghai) Co., Ltd.;Lu Dianyun;Xiao Haiwang CN109354575, 2019, A Location in patent:Paragraph 0030-0033; 0038; 0039; 0040; 0044-0046
6482-24-2
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$9.00/1g
283-56-7
223 suppliers
$28.00/25g
70384-51-9
227 suppliers
$15.00/1g
52808-36-3
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31576-51-9
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$50.00/50mg
70384-51-9
227 suppliers
$15.00/1g
111-77-3
450 suppliers
$10.60/50gm:
70384-51-9
227 suppliers
$15.00/1g
111-77-3
450 suppliers
$10.60/50gm:
![bis[2-(2-methoxyethoxy)ethyl]amine](/CAS/GIF/5732-47-8.gif)
5732-47-8
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70384-51-9
227 suppliers
$15.00/1g