데카메트린

데카메트린
데카메트린 구조식 이미지
카스 번호:
52918-63-5
한글명:
데카메트린
동의어(한글):
데카메트린;델타메트린;3-(2,2-디브롬에텐일)-2,2-디메틸시클로프로판카르복실산시아노(3-펜옥시페닐)메틸에스테르
상품명:
Deltamethrin
동의어(영문):
DELTAMETRIN;Deltamethrine;DECAMETHRIN;DELTAMETHRIN 98%;DEPAR;DECIS;BUTOX;rup987;K-Otek;butoss
CBNumber:
CB5266265
분자식:
C22H19Br2NO3
포뮬러 무게:
505.2
MOL 파일:
52918-63-5.mol

데카메트린 속성

녹는점
98°C
끓는 점
300°C
알파
+56~+64°(20℃/D)(c=4,C6H6)
밀도
1.5214 (rough estimate)
증기압
1.24×10-2Pa (25 °C)
굴절률
1.6220 (estimate)
인화점
-18 °C
저장 조건
−20°C
용해도
DMSO에 용해됨(최대 50mg/ml)
수용성
<0.0002mg l-1(25°C)
물리적 상태
수정 같은
색상
무색의
최대 파장(λmax)
278nm(Hexane)(lit.)
Merck
14,2883
BRN
6746312
안정성
안정적인. 산, 알칼리, 강산화제와 호환되지 않습니다.
LogP
6.200
IARC
3 (Vol. 53) 1991
NIST
Deltamethrin(52918-63-5)
EPA
Deltamethrin (52918-63-5)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 T,N,Xn,F
위험 카페고리 넘버 23/25-50/53-67-65-38-11
안전지침서 24-28-36/37/39-38-45-60-61-62-16
유엔번호(UN No.) UN 2811 6.1/PG 2
WGK 독일 3
RTECS 번호 GZ1233000
위험 등급 6.1(a)
포장분류 II
HS 번호 29269090
유해 물질 데이터 52918-63-5(Hazardous Substances Data)
독성 LD50 in female rats (mg/kg): 31 orally; 4 i.v. (Kavlock)
기존화학 물질 KE-09936
유해화학물질 필터링 97-1-18
함량 및 규제정보 물질구분: 유독물질; 혼합물(제품)함량정보: 데카메트린 및 이를 25% 이상 함유한 혼합물
그림문자(GHS): GHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H410 장기적 영향에 의해 수생생물에 매우 유독함 수생 환경유해성 물질 - 만성 구분 1 경고 GHS hazard pictograms P273, P391, P501
예방조치문구:
P261 분진·흄·가스·미스트·증기·...·스프레이의 흡입을 피하시오.
P264 취급 후에는 손을 철저히 씻으시오.
P264 취급 후에는 손을 철저히 씻으시오.
P270 이 제품을 사용할 때에는 먹거나, 마시거나 흡연하지 마시오.
P273 환경으로 배출하지 마시오.
P301+P310 삼켰다면 즉시 의료기관(의사)의 진찰을 받으시오.
NFPA 704
1
4 0

데카메트린 MSDS


Deltamethrin

데카메트린 C화학적 특성, 용도, 생산

개요

Deltamethrin is a kind of synthetic pyrethroids insecticide used worldwide in agriculture for home pest control and protection of foodstuff and disease vector control. Deltamethrin belongs to the type II pyrethroids, which is hydrophobic in nature. It kills the insects through producing severe delay in sodium channel inactivation, leading to a persistent depolarization of the nerve membrane without repetitive discharge. However, this pesticide can be contained in contaminated food and water, and is readily absorbed by the oral route. Recent studies have shown that it can have certain toxicity through inducing oxidative stress. Vitamin can be used to alleviate its toxicity.

화학적 성질

White Powder

용도

Deltamethrin is effective against a wide range of insects in fruit, cereals, vegetables, cotton, soyabeans and oilseed rape. It is also used for the control of crawling and flying insects indoors, in stored grain and timber and for ectoparasite control on animals.

정의

ChEBI: A carboxylic ester obtained by formal condensation between 3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylic acid and cyano(3-phenoxyphenyl)methanol.

색상 색인 번호

Pyrethroids, also called pyrethrinoids, are neurotoxic synthetic compounds used as insecticides, with irritant properties. Cypermethrin and fenvalerate have been reported as causing positive allergic patch tests, but only fenvalerate was relevant in an agricultural worker.

잠재적 노출

Deltamethrin is a synthetic pyrethroid insecticide that kills insects on contact and through diges- tion. It is used to control a variety of chewing and sucking insects that infest fruit, vegetables and field crops, includ- ing apples, pears and plums; peas, glasshouse cucumbers, tomatoes, peppers, potted plants, and ornamentals; hops, oats, cotton and other field crops. Deltamethrin is also used to control residential and commercial insect pests. Some formulations are RUPs)

환경귀착

Deltamethrin is a type II pyrethroid, a functional neurotoxin slowing the inactivation of voltage-gated sodium channels leading to a state of hyperexcitability which in turn causes fine tremor, salivation, and choreoathetosis. Other proposed contributory actions include antagonism of gammaaminobutyric acid A receptor inhibition and voltage-gated chloride and calcium channels.

신진 대사 경로

After oral administration of 14C-deltamethrin to lactating dairy cows, deltamethrin is metabolized and excreted in the bile and urine with very little accumulation in major edible tissues. The major portion (78-82%) of the radioactivity in feces is deltamethrin. Only 4-6% is eliminated in the urine and 0.42 ? 1.62% is secreted in the milk. The primary biotransformation is via the hydrolysis of the ester linkage followed by oxidation of the geminal methyl groups of cyclopropane carboxylic acids and phenoxy benzaldehyde, resulting in dicarboxylic acid, lactonecarboxylic acid, or phenoxybenzoic acid derivatives. Deltamethrin is not metabolized within algae cells and mouse fibroblasts, but is partially transformed into less or not active isomers. In algae and fibroblast culture media, many metabolites of deltamethrin resulting mostly from hydrolysis of the molecule are found. This metabolism seems to be linked with the release of enzymes by cells into the culture medium.

운송 방법

UN2811 Toxic solids, organic, n.o.s., Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required.UN3349 Pyrethroid pesticide, solid toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

비 호환성

May react violently with strong oxidi- zers, bromine, 90% hydrogen peroxide, phosphorus trichloride, silver powders or dust. Incompatible with silver compounds. Mixture with some silver compounds forms explosive salts of silver oxalate.

폐기물 처리

ncineration would be an effective disposal procedure where permitted. If an efficient incinerator is not available, the product should be mixed with large amounts of combustible material and contact with the smoke should be avoided. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers.

참고 문헌

Adams, A. J. "A review of the efficacy and uses of deltamethrin for wood preservation." Document - the International Research Group on Wood Preservation (Sweden) (1996).
Sayeed, I, et al. "Oxidative stress biomarkers of exposure to deltamethrin in freshwater fish, Channapunctatus Bloch." Ecotoxicology & Environmental Safety 56.2(2003):295-301.
Yousef, Mokhtar I., T. I. Awad, and E. H. Mohamed. "Deltamethrin-induced oxidative damage and biochemical alterations in rat and its attenuation by Vitamin E." Toxicology 227.3(2006):240-247.

데카메트린 준비 용품 및 원자재

원자재

준비 용품


데카메트린 공급 업체

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