메틸 프로피오네이트

메틸 프로피오네이트
메틸 프로피오네이트 구조식 이미지
카스 번호:
554-12-1
한글명:
메틸 프로피오네이트
동의어(한글):
메틸프로필레이트;Methylpropionate;메틸프로피오네이트;메틸프로피온산;메틸프로판오에이트;메틸프로피온에이트;메틸프로피온산(METHYLPROPIONATE);메틸 프로피온에이트;메틸 프로파노에이트;메틸 프로필레이트;프로판산, 메틸 에스터;프로피온산 메틸;프로피온산, 메틸
상품명:
Methyl propionate
동의어(영문):
METHYL PROPANOATE;C3;METHYL PROPYLATE;FEMA 2742;C2H5COOCH3;femanumber2742;METHYLPROPIONAT;TRIANOIC METHYL;METHYL PROPIONATE;propionatedemethyle
CBNumber:
CB8230902
분자식:
C4H8O2
포뮬러 무게:
88.11
MOL 파일:
554-12-1.mol
MSDS 파일:
SDS

메틸 프로피오네이트 속성

녹는점
-88 °C (lit.)
끓는 점
79 °C (lit.)
밀도
0.915 g/mL at 25 °C (lit.)
증기 밀도
3 (vs air)
증기압
40 mm Hg ( 11 °C)
굴절률
n20/D 1.376(lit.)
FEMA
2742 | METHYL PROPIONATE
인화점
43 °F
저장 조건
Store below +30°C.
용해도
H2O: 용해성16부
물리적 상태
액체
색상
무색의
냄새
100.00%에서. 신선한 가혹한 럼 과일 향이 나는 딸기 사과
?? ??
과일 같은
폭발한계
2.5-13%(V)
수용성
20°C에서 5g/100mL
Merck
14,6112
JECFA Number
141
BRN
1737628
Dielectric constant
5.5(19℃)
안정성
안정적인. 가연성이 높습니다. 강한 산화제, 산, 염기와 호환되지 않습니다. 공기와 쉽게 폭발성 혼합물을 형성합니다. 수분에 민감합니다.
LogP
0.8 at 26.6℃
CAS 데이터베이스
554-12-1(CAS DataBase Reference)
NIST
Propanoic acid, methyl ester(554-12-1)
EPA
Methyl propionate (554-12-1)
안전
  • 위험 및 안전 성명
  • 위험 및 사전주의 사항 (GHS)
위험품 표기 F,Xn
위험 카페고리 넘버 11-20-2017/11/20
안전지침서 16-24-29-33
유엔번호(UN No.) UN 1248 3/PG 2
WGK 독일 1
RTECS 번호 UF5970000
자연 발화 온도 876 °F
TSCA Yes
HS 번호 2915 50 00
위험 등급 3
포장분류 II
유해 물질 데이터 554-12-1(Hazardous Substances Data)
독성 LD50 orally in Rabbit: 5000 mg/kg
기존화학 물질 KE-24874
그림문자(GHS): GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
신호 어: Danger
유해·위험 문구:
암호 유해·위험 문구 위험 등급 범주 신호 어 그림 문자 P- 코드
H225 고인화성 액체 및 증기 인화성 액체 구분 2 위험 GHS hazard pictograms P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H318 눈에 심한 손상을 일으킴 심한 눈 손상 또는 자극성 물질 구분 1 위험 GHS hazard pictograms P280, P305+P351+P338, P310
H332 흡입하면 유해함 급성 독성 물질 흡입 구분 4 경고 GHS hazard pictograms P261, P271, P304+P340, P312
예방조치문구:
P210 열·스파크·화염·고열로부터 멀리하시오 - 금연 하시오.
P233 용기를 단단히 밀폐하시오. 용기는 환기가 잘 되는 곳에 단단히 밀폐하여 보관하시오.
P240 용기와 수용설비를 접지 및 접합시키시오.
P280 보호장갑/보호의/보안경/안면보호구를 착용하시오.
P305+P351+P338 눈에 묻으면 몇 분간 물로 조심해서 씻으시오. 가능하면 콘택트렌즈를 제거하시오. 계속 씻으시오.
NFPA 704
3
1 0

메틸 프로피오네이트 C화학적 특성, 용도, 생산

개요

Methyl propionate, also known as methyl propanoate, is a chemical compound with the molecular formula C4H8O2. It is a volatile ester with a sweet, fruity, rum-like odor.

화학적 성질

Methyl propionate is colorless liquid with a sweet, fruity, rum-like odor.

출처

Reported found in guava, honey, melon, pineapple, raspberry, blackberry, strawberry, cheddar cheese, cooked beef, coffee, soy protein, durian (Durio zibethinus), starfruit, plum brandy, cherimoya, kiwifruit, naranjilla, mussels and rooibus tea (Aspalathus linearis)

용도

Methyl propionate is used as a solvent for cellulose nitrate and lacquers, and as a raw material for the production of paints, varnishes and other chemicals such as methyl methacrylate.
Due to its fruity smell and taste, it is also used in fragrances and flavoring.

제조 방법

Methyl propionate can be prepared by esterification of propionic acid with methanol. Industrially, it is prepared by the reaction of ethylene with carbon monoxide and methanol in the presence of nickel carbonyl.

생산 방법

Methyl propionate is produced by the direct esterification of propionic acid with methanol in the presence of concentrated sulfuric acid .

일반 설명

A clear colorless liquid. Flash point 28°F. Density about the same as water. Vapors heavier than air. May irritate skin, eyes, and mucous membranes. Used for flavoring and as a solvent.

공기와 물의 반응

Highly flammable. Soluble in water.

반응 프로필

Methyl propionate reacts with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction with caustic solutions. Flammable hydrogen is generated with alkali metals and hydrides.

위험도

Flammable, dangerous fire risk, explosivelimits in air 2.5–13%.

건강위험

May cause toxic effects if inhaled or absorbed through skin. Inhalation or contact with material may irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

화재위험

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Moderately toxic by ingestion. Mildly toxic by inhalation. A skin irritant. A very dangerous fire hazard when exposed to heat, flame, or oxidizers. Explosive in the form of vapor when exposed to heat or flame. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.

잠재적 노출

Used as a solvent; and in making paints, lacquers, and varnishes. Also used in flavorings and fragrances

운송 방법

UN1248 Methyl propionate, Hazard Class: 3; Labels: 3-Flammable liquid.

Purification Methods

Wash the ester with saturated aqueous NaCl, then dry it with Na2CO3 and distil it from P2O5. (This removes any free acid and alcohol.) It has also been dried with anhydrous CuSO4. [Beilstein 2 IV 104.]

비 호환성

May form explosive mixture with air. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Keep away from heat and moisture.

메틸 프로피오네이트 준비 용품 및 원자재

원자재

준비 용품


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